a State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, School of Geoscience and Technology, Southwest Petroleum University, Chengdu, Sichuan 610500, China; b School of Geoscience and Technology, Southwest Petroleum University, Chengdu 610500, Sichuan, China; c PetroChina Key Laboratory of Carbonate Reservoir, Southwest Petroleum University, Chengdu 610500, Sichuan, China; d State Key Laboratory for Mineral Deposits Research, School of Earth Sciences and Engineering, Nanjing University, Nanjing210023, Jiangsu, China
Abstract Lower Cretaceous black shales in coastal southeastern China are of significance to the geological study of the Tethys and Pacific realms and to hydrocarbon exploration of southeastern China and East China Sea. However, the stratigraphic correlation, distribution patterns and hydrocarbon potential of the black shales have not been well constrained so far. In this study, the zircon U-Pb ages, organic petrologic and geochemical analyses were performed for representative outcrop sections in the region. Zircon U-Pb ages demonstrate that the Lower Cretaceous black shales in coastal southeastern China can be divided into two regional-scale sets. The first set was deposited during the early stage of the Early Cretaceous (K11, Berriasian-Hauterivian). The second set was deposited during the late stage of the Early Cretaceous (K12), and might extend to the Taiwan Strait. Detailed organic geochemical analyses including organic matter abundance, type and maturity of the Lower Cretaceous black shales demonstrate that the organic matter abundance of the sources reached medium to good quality by the hydrocarbon source rock standards, and the average TOC values and the chloroform bitumen “A” of the K11 black shales are higher. The type of organic matter is mainly type III, type II can also be found of the K12 black shales. The thermal maturity of most samples is high to overmature. A relatively comprehensive hydrocarbon resource evaluation indicates that favorable regions are in the northern Guangdong Province for the K11 and in the coastal region of Zhejiang Province and the western Fujian Province for the K12. Sedimentology studies on the Shipu section for the K11 black shales illuminated that the K12 black shales in coastal southeastern China were mainly deposited during transgressive periods. The relative sea level changes controlled the sequential development pattern of the K12 black shales.
Fund:This study was funded by the National Natural Science Foundation of China (Grant No. 41472099).
Corresponding Authors:* Corresponding author.
E-mail: Lower Cretaceous|Black shales, Hydrocarbon potential, development pattern, Southeastern China
Cite this article:
Guang Hu,Wenxuan Hu,Jian Cao et al. The distribution, hydrocarbon potential, and development of the Lower Cretaceous black shales in coastal southeastern China[J]. , 2017, 6(4): 333-351.
Guang Hu,Wenxuan Hu,Jian Cao et al. The distribution, hydrocarbon potential, and development of the Lower Cretaceous black shales in coastal southeastern China[J]. Journal of Palaeogeography, 2017, 6(4): 333-351.
.Andersen, T., 2002. Correction of common Pb in U-Pb analyses that do not report 204Pb. Chemical Geology, 192, 59-79.
[2]
.Bureau of Geology and Mineral Resources of Fujian Province, 1985. Regional Geological Survey of Fujian Province . Beijing: Geological Publishing House. 670p.
[3]
.Bureau of Geology and Mineral Resources of Fujian Province. 1997. Stratigraphy (Lithostratigraphic) of Fujian Province . Beijing: China University of Geosciences Press. 216p.
[4]
.Bureau of Geology and Mineral Resources of Guangdong Province, 1988. Regional geology of Guangdong Province. Beijing: Geological Publishing House. 941p.
[5]
.Bureau of Geology and Mineral Resources of Guangdong Province, 1996. Stratigraphy (Lithostratigraphic) of Guangdong Province. Beijing: China University of Geosciences Press. 264p.
[6]
.Bureau of Geology and Mineral Resources of Jiangxi Province. 1984. Regional Geological Survey of Jiangxi Province . Beijing: Geological Publishing House. 921p.
[7]
.Bureau of Geology and Mineral Resources of Jiangxi Province, 1997. Stratigraphy (Lithostratigraphic) of Jiangxi Province . Beijing: China University of Geosciences Press. 381p.
[8]
.Bureau of Geology and Mineral Resources of Zhejiang Province, 1989. Regional Geological Survey of Zhejiang Province . Beijing: Geological Publishing House. 688p.
[9]
.Bureau of Geology and Mineral Resources of Zhejiang Province, 1996. Stratigraphy (Lithostratigraphic) of Zhejiang Province . Beijing: China University of Geosciences Press. 236p.
Chen, P.J., 2000. Paleoenvironmental changes during the Cretaceous in eastern China. In: Okada, H., Mateer, N.J. (Eds.), Cretaceous Environments of Asia . New York, Elsevier, pp. 81-90.
[12]
Ding, B.L., Li, Y.X., Wang, Y.P., Feng, N.Sh., Zhang,Y., Lan, Sh.X., 2010. Comprehensive Stratigraphical Study and its Progress on Cretaceous System of Zhejiang Province. Beijing: Geological Publishing House. 171p.
[13]
Gilder, S.A., Gill, J., Coe, R.S., Zhao, X.X., Liu, Z.W.,Wang, Yuan, G.X., K.R., Liu, W.L., Kuang, G.D., Wu, H.R., 1996. Isotopic and paleomagnetic constraints on the Mesozoic tectonic evolution of south China. Journal of Geophysical Research, Solid Earth , 101 (B7), 16,137-16,154.
[14]
Hardenbol, J., Thierry, J., Farley, M.B., Jacquin, Th., de Graciansky, P.-C., Vail, P.R., 1998. Mesozoic and Cenozoic sequence chronostratigraphic framework of European basins. In: de Graciansky, P.-C., Hardenbol, J., Jacquin, Th., Vail, P.R. (Eds.), Mesozoic-Cenozoic Sequence Stratigraphy of European Basins. SEPM Special Publication, 60. pp. 3-13.
[15]
Hu, G., Hu, W.X., Cao, J., Yao, S.P., Wang, X.Y., Liu, Y.X., 2011a. The zircon U-Pb dating of the Lower Cretaceous Bantou Formation in western Fujian and stratigraphic correlation. Advances in Earth Science , 26 (9), 28-38 (in Chinese with English abstract).
[16]
Hu, G., Hu, W.X., Cao, J., Yao, S.P., Xie, X.M., Gao, Y.Q., 2011b. Source rock features and resource potential of the Lower Cretaceous Strata in coastal southeast China . Geological Journal of China Universities , 17(2), 206-219 (in Chinese with English abstract).
[17]
Hu, G., Hu, W.X., Cao, J., Yao, S.P., Xie, X.M., Li, Y.X., Liu, Y.X., Wang, X.Y., 2012a. Deciphering the Early Cretaceous transgression in coastal southeastern China: Constraints based on petrography, paleontology and geochemistry. Palaeogeography, Palaeoclimatology, Palaeoecology , 317-318, 182-195.
[18]
Hu, G., Hu, W.X., Cao, J., Yao, S.P., Li, Y.X., Liu, Y.X., Wang, X.Y., 2012b. Zircon U-Pb dating of the Shipu limestone in Zhejiang Province, coastal southeast China: Implications for the Early Cretaceous environment. Cretaceous Research , 37, 65-75.
[19]
Hu, H.G., Hu, S.L., Wang, S.S., Zhu, M., 1982. On the ages of Jurassic and Cretaceous volcanic rocks by the radiometric dating. Acta Geologica Sinica , 4, 315-323 (in Chinese with English abstract).
[20]
Huang, T.C., 1978. Calcareous nannofossils of the subsurface pre-Miocene rocks from the Peikang basement high and adjacent areas in western central Taiwan (Part 1: Cretaceous). Petroleum Geology of Taiwan, 15, 49-87.
[21]
Jackson, S.E., Pearson, N.J., Griffin, W.L., Belousova, E.A., 2004. The application of laser ablation-inductively coupled plasma-mass spectrometry to in situ U-Pb zircon geochronology. Chemical Geology , 211, 47-69.
[22]
Jacquin, T., de Graciansky, P.-C., 1998. Major transgressive-regressive cycles: The stratigraphic signature of European basin development. In: de Graciansky, P.-C., Hardenbol, J., Jacquin, Th., Vail, P.R. (Eds.), MesozoiceCenozoic Sequence Stratigraphy of European Basins. SEPM Special Publication, 60, pp. 15-29.
[23]
Jiang, C.Q., Chen, Z. H., A., Mort, M., Milovic, R., Robinson, R. Stewart, D. L., 2016, Hydrocarbon evaporative loss from shale core samples as revealed by Rock-Eval and thermal desorption-gas chromatography analysis: Its geochemical and geological implications: Marine and Petroleum Geology , 70, 294-303.
[24]
Li, J.H., Zhang, Y.Q., Dong, S.W., Johnston, S.T., 2014. Cretaceous tectonic evolution of South China: A preliminary synthesis. Earth-Science Reviews , 134, 98-136.
[25]
Li, K.Y., Shen, J.L., Wang, X.P., 1989. Chronology of the Mesozoic volcanic rock in the Zhejiang, Fujian, and Jiangxi Provinces. Journal of Stratigraphy , 13(1), 1-13 (in Chinese with English abstract).
[26]
Li, T.D., Mo, J., 2002. Tectonic framework of the west circum-pacific tectonic tract and the geological evolution of the East China Sea. Marine Geology and Quaternary Geology , 22, 1-6 (in Chinese with English abstract).
[27]
Li, W.B., Liu, Z.S., 1994. The Cretaceous palynofloras and their bearing on stratigraphic correlation in China. Cretaceous Research , 15, 333-365.
[28]
Li, X.H., 2000. Cretaceous magmatism and lithospheric extension in Southeast China. Journal of Asian Earth Sciences , 18(3), 293-305.
[29]
Littke, R., U. Klussmann, B. Krooss, D. Leythaeuser, 1991, Quantification of loss of calcite, pyrite, and organic matter due to weathering of Toarcian black shales and effects on kerogen and bitumen characteristics. Geochimica et Cosmochimica Acta , 55(11), 3369-3378.
[30]
Ludwig, K., 2003. User's manual for Isoplot 3.00: A geochronological Toolkit for Microsoft Excel. Berkeley Geochronology Center, Special Publication .
[31]
Luo, Y.D., Yu, Y.W., 2004. Age of the Yongkang Group and regional stratigraphic correlation. Geology in China , 31(4), 395-399 (in Chinese with English abstract).
[32]
Matsumoto, T., 1979. Restudy of phylloceratid ammonite from Peikang. Petroleum Geology of Taiwan, 16, 51-57.
[33]
Nelson, D.R., 2001. An assessment of the determination of depositional ages for Precambrian clastic sedimentary rocks by U-Pb dating of detrital zircon. Sedimentary Geology , 141-142, 37-60.
[34]
Peters, K. E., 1986, Guidelines for evaluating petroleum source rock using programmed pyrolysis. AAPG Bulletin , 70(3), 318-329.
[35]
Schoenherr, J., R. Littke, J. L., Urai, P. A. Kukla, Z., Rawahi, 2007, Polyphase thermal evolution in the Infra-Cambrian Ara Group (South Oman Salt Basin) as deduced by solid bitumen maturity. Organic Geochemistry , 38(8), 1293-1318.
[36]
Sha, J.G., Hirano H., Yao, X.G., Pan, Y.H., 2008. Late Mesozoic transgressions of eastern Heilongjiang and their significance in tectonics, and coal and oil accumulation in northeast China. Paleogeography, Paleoclimatology, Paleoecology , 263, 119-130.
[37]
Skelton, P.W., Spicer, R.A., Kelley, S.P., Gilmour, I., 2003. The Cretaceous World .
[38]
Su, Y.P., Zheng, J.P., Griffin, W.L., Tang, H.Y., O'Reilly, S.Y., Lin, X.Y., 2010. Zircon U-Pb and Hf isotopes of volcanic rocks from the Batamayineishan Formation in the eastern Junggar Basin. Chinese Science Bulletin , 55(36), 4150 - 4161.
[39]
Tang, S.L., Yan, D.P., Qiu, L., Gao, J.F., Wang, C.L., 2014.Partitioning of the Cretaceous Pan-Yangtze Basin in the central South China Block by exhumation of the Xuefeng Mountains during a transition from extensional to compressional tectonics- Gondwana Research , 25, 1644-1659.
[40]
Taylor, G. H., M. Teichmüller, A. Davis, C. F. K., Diessel, R. Littke, P. Robert, 1998, Organic Petrology . Borntraeger, Berlin-Stuttgart. 704 p.
[41]
The Petroleum Geologic Brigade of State Ministry of Geology and Mineral Resources, 1975. The Geological Tectonic Features and Oil-Gas Prospects of Small Basins in Southeast China. Internal Technical Report of State Ministry of Geology and Mineral Resources (in Chinese) . Beijing: Geological Publishing House. 435p.
[42]
The Petroleum Geologic Brigade of State Ministry of Geology and Mineral Resources, 1966. The Mesozoic-Cenozoic Geological and Tectonic Features and Oil-Gas Distribution in East China. Internal Technical Report of State Ministry of Geology and Mineral Resources (in Chinese). Beijing: Geological Publishing House. 523p.
[43]
The Petroleum Geological Team of Zhejiang Province, 1985, Evaluation of Oil and Gas Resource. Internal Technical Report of State Ministry of Geology and Mineral Resources , p. 1-205 (in Chinese).
[44]
Tissot, B. P., D. H., Welte, 1984, Petroleum Formation and Occurrence: A New Approach to Oil and Gas Exploration. New York, Springer-Verlag.
[45]
Wang, D. Z., Zhou, X. M., 2002. The genesis of the late Mesozoic arkosic volcanic- intrusive igneous rock of the southeast China and the crust evolution. Beijing: China Science and Technology Press, p. 1-17 (in Chinese with English abstract).
[46]
Xie, X.M., Hu, W.X., Cao, J., Yao, S.P., Bian, L.Z., Gao, Y.Q., 2010. Preliminary investigation on depositional environment of black mud in Lower Cretaceous, Zhejiang and Fujian Provinces: Micropaleontology and organic geochemical evidences. Acta Sedimentologica Sinica , 28, 1108-1116 (in Chinese with English abstract).
[47]
Yang, T.S., Ma, Y.M., Zhang, S.H., Bian, W.W., Yang, Z.Y., Wu, H.C., Li, H.Y., Chen, W.W., Ding, J.K., 2014. New insights into the India-Asia collision process from Cretaceous paleomagnetic and geochronologic results in the Lhasa terrane. In Press.
[48]
Yu, Y.W., Xu, B.T., 1999. Stratigraphical sequence and geochronology of the upper Mesozoic volcano sedimentary rock series in Zhejiang. Journal of stratigraphy , 23, 136-145 (in Chinese with English abstract).
[49]
Zhao, X.X., Xiao, W.J., Hébert, R., Wang, C.S., 2012. Plate tectonics of Asia: Geological and geophysical constraints. Gondwana Research, 22, 353-359.
[50]
Zhu, W.L., Wang, G.C., 2010. New venture of exploration of pre-Cenozoic oil and gas in Chinese offshore areas. Earth Science Frontiers , 7, 21-216 (in Chinese with English abstract).