Abstract:As one type of important facies-incaditing grains in carbonate rocks,previous studies on ooids mainly focused on their origin,and there are few studies on diagenetic alternations of ooids. The Cambrian Zhangxia Formation at the Xiaweidian section in Western Hills of Beijing is characterized by a thick succession of oolitic limestone. In this paper,based on outcrop and thin-section observation and combined with geochemical data such as XRD,organic carbon and pyrolysis,we described the features of silicfied oolites,discussed the sources of silica and provided a silicification mechanism. The results show that the dissolution and refilling or neomorphism of ooids resulted in enrichment of organic matter at the edges of the ooids,and the organic acids,released from evolution of organic matter,are the main controlling factors for siliceous precipitation. Silica mainly derives from input of the terrestrial siliciclastics and transformation of clay minerals. Due to the concentration of organic matters and formation of the organic membranes at the edges of the ooids,silica precipitation mainly occurred along the edges of the ooids,forming a specific silicified sheath along ooid edges. The result also suggests that microbes played an important role in the formation of ooids.
Guo Qi-Heng,Jin Zhen-Kui,Zhu Lei et al. Mechanism for silicification of ooid:Example from the Cambrian Zhangxia Formation at Xiaweidian section in Western Hills of Beijing[J]. JOPC, 2019, 21(4): 627-635.
[1] 柴华,胡望水,唐友军,肖传桃,张春明,林小云. 2012. 安徽宿松地区中二叠统栖霞组上升流相烃源岩地球化学特征. 石油天然气学报, 34(3): 1-6. [Chai H,Hu W S,Tang Y J,Xiao C T,Zhang C M,Lin X Y.2012. Geochemistry feature of up-current facies source rocks from Qixia Formation of Middle Permian in the Susong Area of Anhui Province. Journal of Oil and Gas Technology, 34(3): 1-6] [2] 陈永权,蒋少涌,周新源,杨文静,韩利军. 2010. 塔里木盆地寒武系层状硅质岩与硅化岩的元素δ30S、δ18O地球化学研究. 地球化学, 39(2): 159-170. [Chen Y Q,Jiang S Y,Zhou X Y,Yang W J,Han L J.2010. δ30S,δ18O and elements geochemistry on the bedded siliceous rocks and cherts in dolostones from Cambrian strata,Tarim Basin. Geochimica, 39(2): 159-170] [3] 代明月,齐永安,陈尧,李妲. 2014. 豫西渑池地区寒武系第三统张夏组的巨鲕及其成因. 古地理学报, 16(5): 726-734. [Dai M Y,Qi Y A,Chen Y,Li D.2014. Giant ooids and their genetic analysis from the Zhangxia Formation of Cambrian Series 3 in Mianchi area,western Henan Province. Journal of Palaeogeography(Chinese Edition), 16(5): 726-734] [4] 段雄,时志强,金鑫,范鸿,姬国锋. 2015. 巨鲕的微生物成因: 来自重庆石柱地区下寒武统的证据. 古地理学报, 17(2): 241-248. [Duan X,Shi Z Q,Jin X,Fan H,Ji G F.2015. Microbial cause for giant ooids: Evidence from the Lower Cambrian in Shizhu area,Chongqing. Journal of Palaeogeography(Chinese Edition), 17(2): 241-248] [5] 姜楠,范凌霄,刘卉,刘志远,梅冰. 2013. 普光气田滩相储层特征及白云化成因. 天然气地球科学, 24(5): 923-930. [Jiang N,Fan L X,Liu H,Liu Z Y,Mei B.2013. Characteristics of the reef flat facies reservior in the Puguang Gasfield and the origin of dolomitization. Natural Gas Geoscience, 24(5): 923-930] [6] 蒋小琼,管宏林,郑和荣,王恕一,范明,鲍云杰,李凤丽,韩彧. 2014. 四川盆地普光气田飞仙关组白云岩储层成因探讨. 石油实验地质, 36(3): 332-336,345. [Jiang X Q,Guan H L,Zheng H R,Wang S Y,Fan M,Bao Y J,Li F L,Han Y.2014. Discussion on origin of dolomite reservoirs in Feixianguan Formation,Puguang gas field,Sichuan Basin. Petroleum Geology & Experiment, 36(3): 332-336,345] [7] 金民东,谭秀成,李凌,曾伟,连承波,罗冰,山述娇,周涛. 2015. 四川盆地磨溪—高石梯地区下寒武统龙王庙组颗粒滩特征及分布规律. 古地理学报, 17(3): 347-358. [Jin M D,Tan X C,Li L,Zeng W,Lian C B,Luo B,Shan S J,Zhou T.2015. Characteristics and distribution of grain bank of the Lower Cambrian Longwangmiao Formation in Moxi-Gaoshiti area,Sichuan Basin. Journal of Palaeogeography(Chinese Edition), 17(3): 347-358] [8] 景宇轩,刘建波,闫振,孙永超,许振清. 2015. 利用风暴沉积类型恢复海平面变化: 以北京西山下苇甸剖面寒武纪中晚期风暴沉积为例. 古地理学报, 17(5): 653-668. [Jing Y X,Liu J B,Yan Z,Sun Y C,Xu Z Q.2015. Reconstructing sea-level changes from types of storm deposits: An example of the middle and late Cambrian at Xiaweidian Section of Western Hills,Beijing. Journal of Palaeogeography(Chinese Edition), 17(5): 653-668] [9] 康世龙,邵龙义,易琦,赵晓峰,许文茂,鲁静. 2016. 京西下苇甸地区寒武系岩石特征及沉积环境研究. 中国煤炭地质, 28(6): 1-8. [Kang S L,Shao L Y,Yi Q,Zhao X F,Xu W M,Lu J.2016. Study on Cambrian petrology and sedimentary environment in Xiaweidian area,Western Beijing. Coal Geology of China, 28(6): 1-8] [10] 李文恒. 1980. 一种硅质岩成因的初步探讨. 地质论评, 26(5): 442-445. [Li W H.1980. A preliminary discussion on the origin of silical rocks. Geological Review, 26(5): 442-445] [11] 梁薇,牟传龙,周恳恳,葛祥英,陈超,徐鹏辉. 2015. 中上扬子地区寒武纪第三世—芙蓉世古地理. 古地理学报, 17(2): 172-185. [Liang W,Mou C L,Zhou K K,Ge X Y,Chen C,Xu P H.2015. Palaeogeography of the Cambrian Epoch 3-Furongian in the Middle and Upper Yangtze region. Journal of Palaeogeography(Chinese Edition), 17(2): 172-185] [12] 梅冥相. 2011. 华北寒武系二级海侵背景下的沉积趋势及层序地层序列: 以北京西郊下苇甸剖面为例. 中国地质, 38(2): 317-337. [Mei M X.2011. Depositional trends and sequence-stratigraphic successions under the Cambrian second-order transgressive setting in the North China Platform: A case study of the Xiaweidian Section in the western suburb of Beijing. Geology in China, 38(2): 317-337] [13] 梅冥相,梅仕龙. 1997. 华北中寒武世张夏组复合海平面变化旋回层序. 沉积学报,15(4): 7-12. [Mei M X,Mei S L.1997. Cycl ic-sequences of composite sea-level change developed in Zhangxia Formation of Middle-Cambrian in North-China. Acta Sedimentologica Sinica, 15(4): 7-12] [14] 莫静,王兴志,谢林,何施雨,梁静,李加利,敖梅,何川. 2013. 四川盆地碳酸盐岩中硅质特征及其对储层的影响. 地质找矿论丛, 28(3): 419-423. [Mo J,Wang X Z,Xie L,He S Y,Liang J,Li J L,Ao M,He C.2013. Characteristics of silica in carbonate rocks of Sichuan Basin and the impaction to reservoir. Contributions to Geology and Mineral Resources Research, 28(3): 419-423] [15] 苏立萍,罗平,胡社荣,罗忠,刘柳红,房小荣. 2004. 川东北罗家寨气田下三叠统飞仙关组鲕粒滩成岩作用. 古地理学报, 6(2): 182-190. [Su L P,Luo P,Hu S R,Luo Z,Liu L H,Fang X R.2004. Diagenesis of oolitic bank of the Feixianguan Formation of Lower Triassic in Luojiazhai Gas Field,northeastern Sichuan Province. Journal of Palaeogeography(Chinese Edition), 6(2): 182-190] [16] 唐朝晖,曾允孚. 1990. 西秦岭中志留统含铀岩系中硅质岩的岩石学、地球化学及其成因. 岩石学报, 6(2): 62-71. [Tang Z H,Zeng Y F.1990. Petrology,geochemistry and origin of cherts in the uraniferous formations,Middle Silurian West Qinling Range. Acta Petrologica Sinica, 6(2): 62-71] [17] 王恕一,蒋小琼,管宏林,鲍云杰. 2010. 川东北普光气田鲕粒白云岩储层粒内溶孔的成因. 沉积学报, 28(1): 10-16. [Wang S Y,Jiang X Q,Guan H L,Bao Y J.2010. Origin of intragranular dissolution pores of oolite dolomite reservoirs in Puguan Gasfield, northeastern Sichuan Province. Acta Sedimentologica Sinica, 28(1): 10-16] [18] 王英华,杨承运,张秀莲. 1983. 鲕粒的结构变化与成岩作用性质和强度的关系. 沉积学报, 1(2): 77-87. [Wang Y H,Yang C Y,Zhang X L.1983. Relationship between the changes of ooidal texture and the property and strength of diagenesis. Acta Sedimentologica Sinica, 1(2): 77-87] [19] 邢延路,冯李强. 2015. 北京西山下苇甸剖面寒武系徐庄组鲕粒研究. 古地理学报, 17(4): 517-528. [Xing Y L,Feng L Q.2015. A study on ooids in limestones of the Cambrian Xuzhuang Formation at Xiaweidian outcrop in Western Hill of Beijing. Journal of Palaeogeography(Chinese Edition), 17(4): 517-528] [20] 伊海生,曾允孚. 1994. 扬子地台东南大陆边缘上震旦统硅质岩的超微组构及其成因. 地质学报, 68(2): 132-141. [Yi H S,Zeng Y F.1994. Ultramicrofabrics and genesis of Upper Sinian chert on the southeast continental margin of the Yangtze Platform. Acta Geologica Sinica, 68(2): 132-141] [21] 伊海生,曾允孚,夏文杰. 1989. 湘黔桂地区上震旦统沉积相及硅质岩成因研究. 矿物岩石, 9(4): 54-58. [Yi H S,Zeng Y F,Xia W J.1989. Sedimentary facies and origin of bedded siliceous rocks of the Upper Sinain in Hunan,Guizhou and Guangxi Region. Minerals and Rocks, 9(4): 54-58] [22] 张旭,张宁,杨振鸿,鲍征宇,夏文臣. 2009. 北京西山下苇甸中寒武统碳酸盐岩微相及沉积相研究. 地质科技情报, 28(6): 25-30. [Zhang X,Zhang N,Yang Z H,Bao Z Y,Xia W C.2009. Carbonate microfacies and sedimentary facies of middle Cambrian Formation at Xiaweidian Profile in Western Hills,Beijing,China. Geological Science and Technology Information, 28(6): 25-30] [23] 赵爱卫,谭秀成,李凌,罗冰,洪海涛,刘吉伟,王勇,段卓. 2015. 四川盆地及其周缘地区寒武系洗象池群颗粒滩特征及分布. 古地理学报, 17(1): 21-32. [Zhao A W,Tan X C,Li L,Luo B,Hong H T,Liu J W,Wang Y,Duan Z.2015. Characteristics and distribution of grain banks in the Cambrian Xixiangchi Group of Sichuan Basin and its adjacent areas. Journal of Palaeogeography(Chinese Edition), 17(1): 21-32] [24] Batchelor M T,Burne R V,Henry B I,Li F,Paul J.2018. A biofilm and organomineralisation model for the growth and limiting size of ooids. Science Reports, 8(1): 1-9. [25] Chanda S K,Bhattacharyya A,Sarkar S.1976. Early diagenetic chert nodules in Bhander Limestone,Maihar,Satna District,Madhya Pradesh,India. Journal of Geology, 84(2): 213-224. [26] Davies P J,Bubela B,Ferguson J.1978. The formation of ooids. Sedimentology, 25(5): 703-730. [27] Folk R L,Lynch F L.2001. Organic matter,putative nannobacteria and the formation of ooids and hardgrounds. Sedimentology, 48(2): 215-229. [28] Hesse R.1987. Selective and reversible carbonate-silica replacements in Lower Cretaceous carbonate-bearing turbidites of the Eastern Alps. Sedimentology, 34(6): 1055-1077. [29] Hesse R.1989. Silica diagenesis: Origin of inorganic and replacement cherts. Earth-Science Reviews, 26(1): 253-284. [30] Laschet C.1984. On the origin of cherts. Facies, 10(1): 257-289. [31] Mcbride E F.1988. Silicification of carbonate pebbles in a fluvial conglomerate by groundwater. Journal of Sedimentary Research, 58(5): 862-867. [32] Pacton M, Ariztegui D,Wacey D,Kilburn M R,Rollionbard C,Farah R,Vasconcelos C.2012. Going nano: A new step toward understanding the processes governing freshwater ooid formation. Geology, 40(6): 547-550.