Characteristics of metallogenic formation,basin prototype and manganese facies belt of the Permian Maokou Formation in Zunyi area,Guizhou Province
Wang Yang1, Liu Zhi-Chen1,2,3, Chen Deng1,2, Xiao Lin1, Xiao Liang1
1 Geological Brigade 102,Bureau of Geology and Mineral Exploration and Development of Guizhou Province,Guizhou Zunyi 553003,China; 2 School of Earth Sciences,China University of Geosciences(Wuhan),Wuhan 430074,China; 3 Innovation Center of Ore Resources Exploration Technology in the Region Bedrock, Ministry of Natural Resources of People's Republic of China,Guiyang 550081,China
Abstract:In order to improve the exploration efficiency and reduce the risks and costs of prospecting and exploration,a prediction model for deep prospecting of the Permian manganese deposit in Zunyi area,Guizhou Province was established in this paper. In recent years,four geological maps with the scale of 1︰50000 were established through the project of “Mineral Geological Survey and Prospecting Prediction in Zunyi Manganese Mine Integral Exploration Area,Guizhou”,and the manganese ore formation,basin prototype,and manganese facies belt characteristics of the Permian Maokou Formation in Zunyi,Guizhou have been summarized. In this paper,according to different lithological combinations,structural structures,six types of deposition combinations were found in the manganese mineralization period of the Third Member of Maokou Formation,including manganese-rich formation,manganese-poor formation,manganese-bearing formation,clay rock formation,silicified rock formation and biological limestone formation. Furthermore,the characteristics of central facies,transition facies and marginal facies of the manganese ore are summarized. The prototype of the basin was analyzed from the thickness of stratum,silicified breccia,special sedimentary structure,and AMT geophysical signs. The theories mentioned above were used to guide the manganese prospecting. Three fully hidden prospecting target areas have been delineated,which provide a basis for drilling projects. From 2018-2019,four boreholes were constructed in the Xiejiaba prospecting target area and thick manganese ore bodies were found in all boreholes,and more than 22 million tons manganese ore have been detection. This shows that the theoretical and methods presented in this paper are effective for deep prospecting of manganese ore in Zunyi area.
Wang Yang,Liu Zhi-Chen,Chen Deng et al. Characteristics of metallogenic formation,basin prototype and manganese facies belt of the Permian Maokou Formation in Zunyi area,Guizhou Province[J]. JOPC, 2020, 22(5): 989-1000.
[1] 陈文一,王中刚,刘家仁. 2003. 贵州二叠纪岩相古地理与沉积矿产关系. 古地理学报, 5(1): 17-20. [Chen W Y,Wang Z G,Liu J R. 2003. Relationship between lithofacies palaeogeography and sedimentary mineral resources of the two fold strata in Guizhou. Journal of Palaeogeography(Chinese Edition), 5(1): 17-20] [2] 戴传固,郑启钤,陈建书,张慧,代雅然. 2014. 贵州海西—燕山构造旋回期成矿地质背景研究. 贵州地质, 31(2): 82-88. [Dai C G,Zheng Q Q,Chen J S,Zhang H,Dai Y R. 2014. Geological background study of metallogenic in Haixi-Yanshan tectonic cycle in Guizhou. Guizhou Geology, 31(2): 82-88] [3] 何斌,徐义刚,肖龙,王雅玫,王康明,沙绍礼. 2006. 峨眉山地幔柱上升的沉积响应及其地质意义. 地质论评, 6(1): 30-37. [He B,Xu Y G,Xiao L,Wang Y W,Wang K M,Shao S L. 2006. Sedimentary responses to uplift of Emeishan mantle plume and its implications. Geological Review, 6(1): 30-37] [4] 韩忠华,潘家州. 2007. 浅析贵州二叠系锰矿与峨眉山玄武岩之关系. 贵州地质, 24(3): 197-201. [Han Z H,Pan J Z. 2007. Relationship analysis on Permian manganese and Emeishan Basalt in Guizhou. Guizhou Geology, 24(3): 197-201] [5] 何登发,李德生,张国伟,赵路子,樊春,鲁人齐,文竹. 2011. 四川多旋回叠合盆地的形成与演化. 地质科学, 46(3): 589-606. [He D F,Li D S,Zhang G W,Zhao L Z,Fan C,Lu R Q,Wen Z. 2011. Formation and evolution of multi-cycle superposed Sichuan Basin,China. Chinese Journal of Geology, 46(3): 589-606] [6] 李旭兵,曾雄伟,王传尚,刘安,白云山. 2011. 东吴运动的沉积学响应: 以湘鄂西及邻区二叠系茅口组顶部不整合面为例. 地层学杂志, 35(3): 299-304. [Li X B,Zeng X W,Wang C S,Liu A,Bai Y S. 2011. Sedimentary response to the Dongwu Movement: A case of the unconformity on top of the Permian Maokou Formation in the western Hubei-Hunan and neighboring areas. Journal of Stratigraphy, 35(3): 299-304] [7] 刘红军. 2001. 扬子地块西缘古特提斯盆地演化与含锰建造盆控特征. 矿物岩石, 21(3): 109-117. [Liu H J. 2001. Paleo-Tethyan basin evolution and basin-bound feature of Mn-bearing formation in the west margin of Yangtze Plate. Journal of Mineralogy and Petrology, 21(3): 109-117] [8] 刘平,廖友常,殷科华,叶德书,朱华,韩忠华,杨光龙. 2008. 与火山活动有关的热水沉积锰矿: 以贵州二叠纪锰矿为例. 中国地质, 35(5): 992-998. [Liu P,Liao Y C,Yin K H,Ye D S,Zhu H,Han Z H,Yang G L. 2008. Hydrothermal sedimentary manganese deposits associated to volcanic activities: Permian manganese deposit in Guizhou. Geology in China, 35(5): 992-998] [9] 刘巽锋,王庆生,高兴基. 2001. 贵州锰矿地质. 贵阳: 贵州人民出版社. [Liu X F,Wang Q S,Gao X J. 2001. Guizhou Manganese Mine Geology. Guiyang: Guizhou People's Publishing House] [10] 刘志臣,张远国,陈登,刘金海,崔忠强,胡乐宇,钟月丽. 2013. 贵州遵义锰矿区“白泥塘层”硅质岩地球化学特征及其地质意义. 矿物学报, 33(4): 265-270. [Liu Z C,Zhang Y G,Chen D,Liu J H,Cui Z Q,Hu L Y,Zhong Y L. 2013. Geochemical characteristics and geological significance of “white muddy layer”siliceous rocks in Zunyi manganese deposit,Guizhou. Acta Mineralogica Sinica, 33(4): 265-270] [11] 刘志臣,王聪,张远国,范波,陈登,魏泽权,崔忠强. 2015. 贵州遵义锰矿床地球化学特征及成因分析. 矿物学报, 35(4): 481-488. [Liu Z C,Wang C,Zhang Y G,Fan B,Chen D,Wei Z Q,Cui Z Q. 2015. Geochemistry and ore genesis of Zunyi Mn Deposit,Guizhou Province,China. Acta Mineralogica Sinica, 35(4): 481-488] [12] 刘志臣,吴发刚,骆红星,孙远彬,周晓林,陈登,代璨怡. 2016a. CSAMT法在贵州遵义锰矿整装勘查中的运用. 物探与化探, 40(2): 342-348. [Liu Z C,Wu F G,Luo H X,Sun Y B,Zhou X L,Chen D,Dai C Y. 2016a. The application of CSAMT method to monoblock exploration in the Zunyi manganese deposit,Guizhou Province. Geophysical and Geochemical Exploration, 40(2): 342-348] [13] 刘志臣,颜佳新,陈登,钟月丽,骆红星,范耀宏,龙宣霖,李隆富. 2016b. 贵州遵义深溪大型隐伏锰矿床的发现及成因探讨. 地质论评,62(s): 217-218. [Liu Z C,Yan J X,Chen D,Zhong Y L,Luo H X,Fan Y H,Long X L,Li L F. 2016b. Discovery and ore genesis of Zunyi Shenxi large concealed Mn deposit,Guizhou Province,China. Geological Review,62(s): 217-218] [14] 刘志臣,颜佳新,陈登,钟月丽,汪洋,王劲松,崔忠强,龙宣霖,李隆富,魏泽权,秦先进,刘永坤,周晓林,戴文坤,时中越,陈蝶,刘柯,蔡嘉骅. 2017. 贵州遵义锰矿国家整装勘查区地质找矿主要进展及潜力预测. 贵州地质, 34(2): 63-70. [Liu Z C,Yan J X,Chen D,Zhong Y L,Wang Y,Wang J S,Cui Z Q,Long X L,Li L F,Wei Z Q,Qin X J,Liu Y K,Zhou X L,Dai W K,Shi Z Y,Chen D,Liu K,Cai J H. 2017. Main progress and potential prediction of geological prospecting of manganese ore in national fully equipped exploration area of Zunyi,Guizhou Province. Guizhou Geology, 34(2): 63-70] [15] 刘志臣,周琦,颜佳新,汪洋,陈登,钟月丽,秦先进. 2019. 二叠纪贵州遵义次级裂谷盆地结构及其对锰矿的控制作用. 古地理学报, 21(3): 517-526. [Liu Z C,Zhou Q,Yan J X,Wang Y,Chen D,Zhong Y L,Qin X J. 2019. Structure of Zunyi rift basin in Guizhou Province during the Permian and its controlling on manganese deposits. Journal of Palaeogeography(Chinese Edition), 21(3): 517-526] [16] 陶平,杜昌乾,马荣,朱华,杜芬应,韩中华,廖莉萍. 2005. 贵州及邻区二叠系锰矿地质特征及成矿作用探讨. 贵州地质, 22(2): 103-108. [Tao P,Du C Q,Ma R,Zhu H,Du F Y,Han Z H,Liao L P. 2005. Geological characteristics and mineralization of Permian manganese deposits in Guizhou and its adjacent areas. Guizhou Geology, 22(2): 103-108] [17] 王涛,计文化,胡建民,李建星,胡道功,童英. 2016. 专题地质填图及有关问题讨论. 地质通报, 35(5): 633-641. [Wang T,Ji W H,Hu J M,Li J X,Hu D G,Tong Y. 2016. Geological mapping for special issues and a discussion on related topics. Geological Bulletin of China, 35(5): 633-641] [18] 王砚耕. 2000. 贵州西南部红土型金矿. 贵州: 贵州科技出版社. [Wang Y G. 2000. Lateritic gold deposits in southwestern Guizhou. Guizhou: Guizhou Science and Technology Publishing House] [19] 王砚耕,陈建书,陈启飞. 2018. 贵州构造—建造划分及其意义. 贵州地质, 35(3): 167-170. [Wang Y G,Chen J S,Chen Q F. 2018. Structure-formation division and its significance of Guizhou. Guizhou Geology, 35(3): 167-170] [20] 汪洋,刘志臣,陈登,钟月丽,秦先进. 2018. 贵州遵义二叠纪锰矿气液喷口群的发现及地质意义. 贵州地质, 35(2): 81-87,95. [Wang Y,Liu Z C,Chen D,Zhong Y L,Qin X J. 2018. Discovery and geological significance of submarine hydrothermal vent in Zunyi manganese deposit,Guizhou. Guizhou Geology, 35(2): 81-87,95] [21] 杨炳南,胡祥云,周琦,沈小庆,何帅,谢小峰,王家俊. 2018. 华南南华纪古天然气渗漏沉积型锰矿AMT勘查技术方法研究. 贵州地质, 35(4): 105-111. [Yang B N,Hu X Y,Zhou Q,Shen X Q,He S,Xie X F,Wang J J. 2018. An audio-frequency magnetotellurics method study on the exploration technology of ancient natural gas seepage sedimentary-type manganese deposit of Nanhua Period in South China. Guizhou Geology, 35(4): 105-111] [22] 杨瑞东,程玛莉,魏怀瑞. 2009. 贵州水城二叠系茅口组含锰岩系地质地球化学特征与锰矿成因分析. 大地构造与成矿学, 32(4): 613-619. [Yang R D,Cheng M L,Wei H R. 2009. Geochemical characteristics and origin of a manganese deposit in the Middle Permian Maokou Formation in Shuicheng,Guizhou,China. Geotectonica et Metallogenia, 32(4): 613-619] [23] 杨瑞东,程玛莉,高军波,徐海,李军,陈军,刘坤. 2018. 贵州二叠系茅口组顶部锰矿沉积特征及矿床成因研究. 地质学报, 92(4): 804-816. [Yang R D,Cheng M L,Gao J B,Xu H,Li J,Chen J,Liu K. 2018. The sedimentary characteristics and origin of manganese deposit in the Middle Permian Maokou Formation in Guizhou,China. Acta Geologica Sinica, 92(4): 804-816] [24] 杨坤光,李学刚,戴传固,张慧,周琦. 2012. 断层调整与控制作用下的叠加构造变形: 以贵州地区燕山期构造为例. 地质科技情报, 31(5): 50-56. [Yang K G,Li X G,Dai C G,Zhang H,Zhou Q. 2012. Superimposition deformation controlled and adjusted by faults: An example from Yanshanian structural deformation in Guizhou Province. Geological Science and Technology Information, 31(5): 50-56] [25] 翟裕生,张湖,宋鸿林,邓军,程小久. 1997. 大型构造与超大型矿床. 北京: 地质出版社,1-175. [Zhai Y S,Zhang H,Song H L,Deng J,Cheng X J. 1997. Large Structure and Superlarge Deposit. Beijing: Geological Publishing House,1-175] [26] 张国伟,郭安林,王岳军,李三忠,董云鹏,刘少峰,何登发,程顺有,鲁如魁,姚安平. 2013. 中国华南大陆构造与问题. 中国科学: 地球科学, 43(10): 1553-1582. [Zhang G W,Guo A L,Wang Y J,Li S Z,Dong Y P,Liu S F,He D F,Cheng S Y,Lu R K,Yao A P. 2013. Tectonics of South China continent and its implications. Science China: Earth Sciences, 43(10): 1553-1582] [27] 张进,贺振宇,曲军峰,张庆龙,李锦轶,郑荣国,张北航,赵衡,解国爱,刘建峰. 2018. 基岩区构造地质填图方法思考、实践、探索. 地质通报, 37(2): 192-221. [Zhang J,He Z Y,Qu J F,Zhang Q L,Li J Y,Zheng R G,Zhang B H,Zhao H,Xie G A,Liu J F. 2018. The structural mapping in exposed bedrock areas: Methods,practice and exploration. Geological Bulletin of China, 37(2): 192-221] [28] 周琦,杜远生,覃英. 2013. 古天然气渗漏沉积型锰矿床成矿系统与成矿模式: 以黔湘渝毗邻区南华纪“大塘坡式”锰矿为例. 矿床地质, 32(3): 457-466. [Zhou Q,Du Y S,Qin Y. 2013. Ancient natural gas seepage sedimentary-type manganese metallogenic system and ore-forming model: A case study of‘Datangpo type’ manganese deposits formed in rift basin of Nanhua Period along Guizhou-Hunan-Chongqing border area. Mineral Deposits, 32(3): 457-466] [29] 周琦,杜远生,袁良军,张遂,余文超,杨胜堂,刘雨. 2016. 黔湘渝毗邻区南华纪武陵裂谷盆地结构及其对锰矿的控制作用. 地球科学, 41(2): 177-188. [Zhou Q,Du Y S,Yuan L J,Zhang S,Yu W C,Yang S T,Liu Y. 2016. The structure of the Wuling rift basin and its control on the manganese deposit during the Nanhua Period in Guizhou-Hunan-Chongqing border area,South China. Earth Science, 41(2): 177-188] [30] 周琦,杜远生,袁良军,张遂,杨炳南,潘文,余文超,王萍,徐源,齐靓,刘雨,覃永军,谢小峰. 2017. 古天然气渗漏沉积型锰矿床找矿模型: 以黔湘渝毗邻区南华纪“大塘坡式”锰矿为例. 地质学报, 91(10): 2285-2298. [Zhou Q,Du Y S,Yuan L J,Zhang S,Yang B N,Pan W,Yu W C,Wang P,Xu Y,Qi L,Liu Y,Qin Y J,Xie X F. 2017. Exploration models of ancient natural gas seep sedimentary-type manganese ore deposit: A case study of the Nanhua Period “Datangpo”type manganese ore in the conjunction area of Guizhou,Hunan and Chongqing. Acta Geologica Sinica, 91(10): 2285-2298] [31] 朱洪发,秦德余,刘翠章. 1989. 论华南孤峰组和大隆组硅质岩成因、分布规律及其构造机制. 石油实验地质, 11(4): 341-348. [Zhu H F,Qin D Y,Liu C Z. 1989. On the origin,distributive pattern and tectonic control of siliceous rocks in Gufeng and Dalong Formations,South China. Petroleum Geology & Experiment, 11(4): 341-348] [32] Attwa M,Henaish A. 2018. Regional structural mapping using a combined geological and geophysical approach: A preliminary study at Cairo-Suez district,Egypt. Journal of African Earth Sciences,144: 104-121. [33] Bernhard S,Olaf D. 2012. Dissolved reactive manganese at pelagic redox clines(part Ⅰ): A method for determination based on field experiments. Journal of Marine Systems, 90(1): 23-30. [34] Childs C, Nicol A,Walsh J J, Watterson J. 2003. The growth and propagation of synsedimentary faults. Journal of Structural Geology, 25(4): 633-648 [35] Edmond J M,von Damm K. 1983. Hot springs on the ocean floor. Scientific American, 248(4): 70-85. [36] Kuznetsov V G. 2017. Evolution of sedimentary rock formation of a rock association level. Doklady Earth Sciences, 475(1): 736-738. [37] He B,Xu Y G,Chung S L,Xiao L,Wang Y M. 2003. Sedimentary evidence for a rapid,kilometer scale crustal doming prior to the eruption of the Emeishan flood basalts. Earth Planet Science Letters, 213: 391-405. [38] Kruse F A,Perry S L. 2013. Mineral mapping using simulated world-view-3 short-wave-infrared imagery. Remote Sensing, 5(6): 2688-2703. [39] Maynard J B. 2003. Manganiferous sediments,rocks,and ores. In: Heinrich D H,Karl K T(eds). Treatise on Geochemistry. Oxford: Pergamon, 20(2): 289-308. [40] Shellnutt J G,Zhou M F. 2006. Rifting-related,Permian ferrosyenites in the Panxi region of the Emeishan large igneous province,SW China. Geochimica et Cosmochimica Acta,70(18,Supplement): A579. [41] Shellnutt J G,Zhou M F,Chung S L. 2010. The Emeishan large igneous province: Advances in the stratigraphic correlations and petrogenetic and metallogenic models. Lithos, 119(1-2): 34-46. [42] Wang X X,Wang T,Ke C H,Yang Y,Li J B,Li Y H,Qi Q J,Lü X Q. 2014. Nd-Hf isotopic mapping of Late Mesozoic granitoids in the East Qinling Orogen,Central China: Constraint on the basements of terranes and distribution of Mo mineralization. Journal of Asian Earth Sciences, 103: 169-183. [43] Zeng J W,Xu R,Gong X M. 2011. Hydrothermal activities and seawater acidification in the Late Devonian F-F transition: Evidence from geochemistry of rare earth elements. Science China: Earth Science, 54(2): 540-549. [44] Zhang Z C,Mao J W,Saunders A D,Ai Y,Li Y,Zhao L. 2009. Petrogenetic modeling of three mafic-ultramafic layered intrusions in the Emeishan large igneous province,SW China,based on isotopic and bulk chemical constraints.Lithos, 113(3-4): 369-392.