Element geochemical characteristics of the reticulate red clay in southern China and its significance for the formation proccess of reticulated mottles
Xu Chuanqi1, Liao Fuqiang1, 2, Jia Yulian1, 2, Huang Siyuan1, Lian Licong1, Ling Chaohao1, Long Jin1
1 Department of Geography and Environment,Jiangxi Normal University,Nanchang 330022,Jiangxi; 2 Ministry Education Key Laboratory of Poyang Lake Wetland and Watershed Research,Nanchang 330022,Jiangxi
Abstract:Reticulate red clay in southern China is a kind of special stratum that formed in a monsoon climate condition,which is of great significance to reconstruct the Quaternary climate environment. For a long time,there is a lack of adequate understanding of physical and chemical characteristics of the formation process of reticulated mottles. Three sections of reticulate red clay,which were located in the Jiujiang and Pengze of Jiangxi Province, and Yueyang of Hunan Province, were studied, and the red matrix and the white reticulated mottles were separated and the geochemical elements,free iron content and so on were analysed. The results show that:(1)In the white reticulated mottles, Fe,Mn,Th,Ga,Cu,Zn,Co,Ni,Cr,V elements are outstanding leaching,while Zr,SiO2,Hf and light rare earth elements are obvious enriched,and the content of free iron are low; in the red matrix, they are reversed. (2)Fe2+ content is higher in the white reticulate,while lower in the matrix,which indicates white reticulate tend to be developed in a reductive environment and matrix tend to be developed in an oxidized environment. The difference of oxidation reduction between white reticulated mottles and red matrix is supposed to be the reason why Fe,Mn,Co,Ni,Cr,V,Zn,Th,Ga,Cu are leaching in the white reticulated mottles and enriched in the matrix, which cause Zr,SiO2 and light rare earth elements relative enriched in the white reticulated mottles and “dilution” in the red matrix.
Xu Chuanqi,Liao Fuqiang,Jia Yulian et al. Element geochemical characteristics of the reticulate red clay in southern China and its significance for the formation proccess of reticulated mottles[J]. JOPC, 2016, 18(5): 865-878.
[1] 陈骏,安芷生,刘连文,季峻峰,杨杰东,陈旸. 2001. 最近2.5,Ma以来黄土高原风尘化学组成的变化与亚洲内陆的化学风化. 中国科学(D辑:地球科学),31(2):136-145. [Chen J,An Z S,Liu L W,Ji J F,Yang J D,Chen Y. 2001. Recently since the 2.5,Ma on the loess plateau over the Asian inland with the change of chemical composition of chemical weathering. The Science of China(D),31(2):136-145] [2] 符连社,任惠娟,李晓智,任英. 1997.4,7-二苯基-1,10-菲罗琳作显色剂水相吸光光度法测定铁价态. 理化检验(化学分册),33(12):548-549. [Fu L S,Ren H J,Li X J,Ren Y. 1997.4,7-diphenyl-1,10-Fe rowling as chromogenic agent water absorption spectrophotometry,and valence state of iron. Archies of Physical and Chemical Inspection(chemical),33(12):548-549] [3] 高剑锋,陆建军,赖鸣远,林雨萍,濮巍. 2003. 岩石样品中微量元素的高分辨率等离子质谱分析. 南京大学学报(自然科学),39(6):844-850. [Gao J F,Lu J J,Lai M Y,Lin Y P,Pu W. 2003. Analysis of trace elements in rock samples using HR-ICPMS. Journal of Nanjing University(Natural Sciences),39(6):844-850] [4] 胡雪峰,龚子同. 2001. 江西九江泰和第四纪红土成因的比较研究. 土壤学报. 38(01):1-9. [Hu X F,Gong Z T. 2001. Comparative study on the origin of quaternary red earth in Jiujiang and Taihe,Jiangxi Province. Acta Pedologica Sinica,38(1):1-9] [5] 胡雪峰,沈铭能,方圣琼. 2004. 皖南网纹红土的粒度分布特征及古环境意义. 第四纪研究,24(2):160-166. [Hu X F,Shen M N,Fang S Q. 2004. Grain-size distribution of the reticulate red clay in southern Anhui Provience and its paleo-environmental significance. Quaternary Sciences,24(2):160-166] [6] 胡雪峰,朱煜,沈铭能. 2005. 南方网纹红土多元成因的粒度证据. 科学通报,50(9):918-925. [Hu X F,Zhu Y,Sheng M N. 2005. The reticulate red clay granularity evidence of multiple reason. Chinese Science Bulletin,50(9):918-925] [7] 胡亚萍,贾玉连,张智,彭学敏,凌光久,王鹏岭. 2013. 粒度揭示的末次间冰期以来长江中游风沙—风尘体系. 中国沙漠,33(5):1324-1332. [Hu Y P,Jia YL,Zhang Z,Peng X M,Lin G J,Wang P L. 2013. Sand-loess system in the middle reaches of Yangtze river since late interglacial indicated by grain size. Journal of Desert Research,33(5):1-9] [8] 黄镇国,张伟强. 1996. 中国南方红色风化壳. 北京:海洋出版社,138-144. [Huang Z G,Zhang W Q. 1996. Red Clay and Red Residuum in South China. Beijing:China Ocean Press,138-144] [9] 蒋复初,吴锡浩,肖华国,赵志中,王苏民,薛滨. 1997. 九江地区网纹红土的时代. 地质力学学报,3(4):27-32. [Jiang F C,Zhu X Y,Xiao H G,Zhao Z Z,Wang S M,Xue B. 1997. Age of the verm iculated red soil in Jiujiang area,central China. Journal of Geom Echanics,3(4):27-32] [10] 李长安,顾延生. 1997. 江西修水第4系网纹红土的地层学研究. 地层学杂志,8(3):227-232. [Li C A,Gu Y S. 1997. Stratigraphic study on the vermicular red earth at Xiushui County,Jiangxi Provience. Journal of Stratigraphy,8(3):227-232] [11] 李徐生,韩志勇,杨达源,陈曰友. 2006. 镇江下蜀黄土的稀土元素地球化学特征研究. 土壤学报,43(1):1-7. [Li X S,Han Z Y,Yang D Y,Chen Y Y. 2006. Ree geochemistry of xiashu loess in Zhengjiang,Jiangsu Provience.Acta Pedologica Sinica,43(1):1-7] [12] 李驭亚. 1965. 华南第四纪网状红土虫状白斑的成因探讨. 地质论评,23(2):144-145. [Li Y Y. 1965. The Quaternary of causes of worm shape white spot of plinthitic red earth in the sourthern China,Geological Review,23(2):144-145] [13] 刘东生,安芷生,郑洪波. 1985. 黄土与环境. 北京:科学出版社,106-112. [Liu D S,An Z S,Zheng H B. 1985. [Loess and Environment. Beijing:Science Press. 106-112] [14] 刘英俊,曹励明. 1984. 元素地球化学导论. 北京:科学出版社,57-80. [Liu Y J,Cao J L. 1984. The Introductory Theory of Geochemical Element. Beijing:Science Press,57-80] [15] 鲁如坤. 2000. 土壤农业化学分析方法. 中国农业出版社,82-83. [Lu R K. 200. Soil Agricultural Chemical Analysis Method. China Agriculture Press,82-83] [16] 毛龙江,莫多闻,杨兢红,史辰義. 2008. 环洞庭湖地区网纹红土中稀土元素的地球化学特征. 环境化学,27(2):222-225. [Mao L J,Mo D W,Yang J H,Shi C Y. 2008. Rare earth element geochemistry of reticulate red clay around Dongting Lake. Environmental Chemistry,27(2):222-225] [17] 王春林. 1986. 湖南第4系蠕虫状网纹红土的成因及其对新构造运动研究的意义. 湖南师范大学自然科学报,9(1):100-106. [Wang C L. 1986. On the origin of Quaternary worm-like net-veined red(laterite)soil in Hunan Provience and its significance in neotectonic studies. Nat Sci J Hunan Normal University,50(9):100-106] [18] 谢树成,易轶,刘育燕,顾延生,马振兴,林文姣,王先彦,刘刚,梁斌,朱宗敏. 2003. 中国南方更新世网纹红土对全球气候变化的响应:分子化石记录. 中国科学(D 辑),33(5):412-417. [Xie S C,Yi Y,Liu Y Y,Gu Y S,Ma Z X,Lin W J,Wang X Y,Liu G,Liang B,Zhu Z M. 2003. Pleistocene reticulate red clay in southern China respond to global climate change:Molecular fossil record. The science of China(D),33(5):412-417] [19] 熊尚发,丁仲礼,刘东生. 2000. 南方红土网纹:古森林植物根系的土壤学证据. 科学通报,45(12):1317-1321. [Xiong S F,Ding Z L,Liu D S. 2000. The worm-shaped veins in the red earth of South China:Pedological evidence for root traces of past forest. Chinese Science Bulletin,45(12):1317-1321] [20] 叶玮,朱丽东,李凤全,杨立辉,Shinji Kanayama,Sadayo Yabuki. 2008. 中国中亚热带网纹红土的地球化学特征与沉积环境. 土壤学报,45(3):385-391. [Ye W,Zhu L D,Li F Q,Yang L H,Shinji Kanayama,Sadayo Yabuki. 2008. Sedimentary environment of vermicular red earth in Mid-subtropical China. Acta Pedologica Sinica,45(3):385-391] [21] 尹秋珍,郭正堂. 2006. 中国南方的网纹红土与东亚季风的异常强盛期. 科学通报,51(2):186-193. [Yin Q Z,Guo Z T. 2006. Mid-Pleistocene vermiculated red soils in southern China as an indication of unusually strengthened East Asian momsoon. Chinese Science Bulletin,51(2):186-193] [22] 张建新,鲁江,邢旭东,申志军,吕焕哲,张国梁. 2007. 湖南洞庭湖地区红土的元素地球化学特征及其指示意义. 地质通报,26(11):1435-1444. [Zhang J X,Lu J,Xing X D,Shen Z J,Lü H Z,Zhang G L. 2007. Element geochemistry of laterite in the Dongting La ke area,Hunan,China and its indicative significance. Geological Bulletin of China,26(11):1435-1444] [23] 张智,贾玉连,彭学敏,凌光久,王鹏岭. 2014. 赣北鄱阳湖地区黄土元素地球化学特征研究. 长江流域资源与环境,23(8):1125-1131. [Zhang Z,Jia Y L,Peng X M,Ling G J,Wang P L. 2014. The study of chemical weather intensity in north Poyang lake region. Resources and Environment in the Yangtze River,23(8):1125-1131] [24] 赵其国,王振权,刘兆礼. 1983. 中国富铝化土壤发生特性的初步研究. 土壤学报,20(4):333-347. [Zhao Q G,Wang Z Q,Liu Z L. 1983. Preliminary studies on genetic properties of the allitic soils in China. Acta Pedologica Sinica,20(4):333-347] [25] 朱景郊. 1988. 网纹红土的成因及其研究意义. 地理研究.,7(4):12-20. [Zhu J J. 1988. Genesis and research significance of the plinthitic horizon. Geographical Research,7(4):12-20] [26] 朱丽东,周尚哲,叶玮,李凤全,王天阳. 2007. 网纹红土稀土元素地球化学特征的初步研究. 中国沙漠,27(2):194-200. [Zhu L D,Zhou S Z,Ye Wei,Li F Q,Wang T Y. 2007. Preliminary study on geochemical behavior of rare earth element of Plinthitic red earth in south China. Journal of Desert Research,27(2):194-200] [27] Coelho M R. 2001. Macro and micromorphology of nodular ferricretes developed over sandstone in the north of Sao Pauld,Brizil. Brazilian Soil Science Society,25:371-385. [28] Eze P N,Udeigwe T K, Meadows M E. 2014. Plinthite and Its Associated Evolutionary Forms in Soils and Landscapes:A Review. Pedosphere,24:153-166. [29] FAO of the UN. 2006. World reference base for soil resources 2006:A framework for international classification,correlation and communication. World Soil Resources Reports, Rome Food and Agriculture Organization:No.103. [30] Lucia H C. Dos Anjos. Franzmeier D P,Schulze D G. 1995. Formation of soil with plithite on a topsequence in Maranhao State,Brazil. Geoderma,64:257-279. [31] Martins S L,Oliveira A P,Moura E G. 2012. Surface infiltration on tropical plinthosols in Maranho,Brazil. In: Lee T S(ed). Water Quality,Soil and Managing Irrigation of Crops. Rijeka, Croatia: InTech,149-160. [32] Mehra O P,Jackson M L. 1960. Iron oxide removal from soils and clays by a dithionite-cirtrate system buffered with sodium biearbonate. Clays and Clay Minerals,7:317-327. [33] Rellini Ⅰ,Trombino L,Firpo M. 2007. Geomorphological context of“plinthitic paleosols”in the mediterranean region:Examples from the coast of western Liguria(northern Italy). Revista Mexicana Ciencias Geológicas, 21:27-40. [34] Rosolen V, Lamotte M, Boulet R, Trichet J, Rouer O, José Melfi A. 2002. Genesis of a mottled Horizon by Fe-depletion within a laterite cover in the Amazon Basin. Comptas Randus Geoscience, 334:187-195. [35] Sombroek W G. 1987. Variations in Contents and Forms of Sesquioxides in “Lateritic”Soils. International Soil Reference and Information Centre. Germany. Http:∥www.isric.org/webdocs/docs/ISRIC_Report_1987_05 pdf. [36] Taylor G,Eggleton R A. 2001. Regolith Geology and Geomorphology. New York:John Wiley and Sons,Ltd,11:145-156. [37] Taylor S R,McLennan S M,Armstrong R L,Tarney J. 2014. The composition and evolution of the continental rocks crust:Rare earth element evidence from sedimentary rocks. Philosophical Transactions of the Royal Society,11:380-399. [38] Young C C,Bien M N,Lee Y Y. 1938. “Red beds”of Hunan. Bulletin of the Geologieal Soeiety China,18:259-300. [39] Zhang J R,Lai Z P,Jia Y L. 2012. Luminescence chronology for late levels of enclosed Huangqihai lake in East Asian monsoon marginal area in northern China. Quaternay Geochronolohy,10:123-128.