Formation environment and mineralization mechanism of oil shale in continental basins of China
Liu Zhao-Jun1,2, Sun Ping-Chang1,2
1 College of Earth Sciences,Jilin University,Changchun 130061,China; 2 Key Laboratory for Oil Shale and Coexisting Minerals of Jilin Province,Jilin University,Changchun 130061,China
Abstract In the past ten years,great progress has been made in the exploration,development and formation theory of oil shale. Based on previous research and systematic investigation,we summarized the formation environment and mineralization mechanism of continental oil shale in China. In general,the oil shale preferably forms in the atmospheric background with relatively high O2 and low CO2 concentration, with four main mineralization mechanisms. In the basins,the tectonic and paleoclimate control the deposit scale of oil shale,resulting in deep-water oil shale formed in balance filled environment,and shallow water oil shale in the over filled environment. The deep water oil shale was deposited in the semi-deep and deep lake environment,where the lake bottom is in the state of hypoxia to anoxia. The biological productivity is the key factor to control the quality of oil shale,and the duration of favorable conditions and the range of low oxygen area determine the scale of oil shale deposit. Shallow water oil shale was deposited in limnetic environment. Lakes with eutrophication and turbid algae are the premises of shallow water oil shale deposition. The restoration of lake itself and paleoclimate regulation result in thin thickness and strong horizontal and vertical heterogeneity of oil shale. Some geological events promoted oil shale deposition and mineralization. For example,anoxia,volcanism,hydrothermal and marine transgression events help to improve bioproductivity and form anoxic environment. Based on the analyses of oil shale forming environment,the mineralization mechanism of deep water and shallow water oil shale is summarized. Combined with the regional tectonic evolution of the China continent,the temporal and spatial distribution of oil shale in China is mainly controlled by the influence of Paleo-Asia,Tethys and Circum-Pacific tectonic domains.
Fund:Financially supported by the National Natural Science Foundation of China(Nos.41772092, 41402088)
Corresponding Authors:
Sun Ping-Chang,born in 1985,is an associate professor in College of Earth Sciences,Jilin University.Now he is engaged in mineralization theory of oil shale.E-mail: sunpingchang711@126.com.
About author: Liu Zhao-Jun,born in 1951,is a professor in College of Earth Sciences,Jilin University.Now he is engaged in sedimentology,mineralization theory of oil shale and resource evaluation.E-mail: liuzj@jlu.edu.cn.
Cite this article:
Liu Zhao-Jun,Sun Ping-Chang. Formation environment and mineralization mechanism of oil shale in continental basins of China[J]. JOPC, 2021, 23(1): 1-17.
Liu Zhao-Jun,Sun Ping-Chang. Formation environment and mineralization mechanism of oil shale in continental basins of China[J]. JOPC, 2021, 23(1): 1-17.
[1] 曹新星,宋之光,李艳,王丽. 2016. 茂名油页岩沉积有机质特征及古气候意义. 地学前缘, 23(3): 243-252. [Cao X X,Song Z G,Li Y,Wang L.2016. The characteristics of organic matter in Maoming oil shales and their paleoclimate significance. Earth Science Frontiers, 23(3): 243-252] [2] 邓晋福,莫宣学,Flower M F J,苏尚国,罗照华,赵海玲,赵志丹,喻学惠,刘翠. 2005. 白垩纪大火成岩省与地幔对流. 地学前缘, 12(2): 217-221. [Deng J F,Mo X X,Flower M F J,Su S G,Luo Z H,Zhao H L,Zhao Z D,Yu X H,Liu C.2005. Cretaceous Large Igneous Provinces and mantle convection. Earth Science Frontiers,2005, 12(2): 217-221] [3] 杜佰伟,谢尚克,董宇,彭清华,郑博. 2016. 伦坡拉盆地渐新统丁青湖组油页岩特征及其地质意义. 吉林大学学报(地球科学版), 46(3): 671-680. [Du B W,Xie S K,Dong Y,Peng Q H,Zheng B.2016. Characteristics of oil shale of Oligocene Dingqinghu Formation and its geological significance,Lunpola Basin. Journal of Jilin University(Earth Science Edition), 46(3): 671-680] [4] 冯子辉,方伟,王雪,黄春艳,霍秋立,张居和,黄清华,张蕾. 2009. 松辽盆地海侵制约油页岩形成的微体古生物和分子化石证据. 中国科学(D辑: 地球科学), 39(10): 1375-1386. [Feng Z H,Fang W,Wang X,Huang C Y,Huo Q L,Zhang J H,Huang Q H,Zhang L.2009. Microfossils and molecular records in oil shales of the Songliao Basin and implications for paleo-depositional environment. Science in China(Series D: Earth Sciences), 39(10): 1375-1386] [5] 傅家谟,徐芬芳,陈德玉,刘德汉,胡成一,贾蓉芬,徐世平,Brassell A S,Eglinton G.1985. 茂名油页岩中生物输入的标志化合物. 地球化学,(2): 99-114. [Fu J M,Xu F F,Chen D Y,Liu D H,Hu C Y,Jia R F,Xu S P,Brassell A S,Eglinton G.1985. Biomarker compounds of biological inputs in Maoming Oil Shale. Geochimica, (2): 99-114] [6] 郭树才,韩威,黄光伟,胡浩权,王锐,Kurt H,Achim W.1988. 中国几种油页岩超临界萃取研究. 化工学报,(2): 198-205. [Guo S C,Han W,Huang G W,Hu H Q,Wang R,Kurt H,Achim W.1988. Experimental study on supercritical extraction of Chinese Oil Shales to yield liquid products. Journal of Chemical Industry and Engineering(China), (2): 198-205] [7] 郭巍,李成博,宋玉勤,马祥县,刘春生. 2006. 民和盆地炭山岭油页岩特征及成矿控制因素分析. 吉林大学学报(地球科学版), 36(6): 923-927,932. [Guo W,Li C B,Song Y Q,Ma X X,Liu C S.2006. Analysis on the characteristics of the oil shale in the Tanshanling Area,Minhe Basin and their mineralization controlling factors. Journal of Jilin University(Earth Science Edition), 36(6): 923-927,932] [8] 郭文秀,温志良,刘建民,赵志,刘忠,郭喜军. 2013. 吉林省油页岩. 长春: 吉林科学技术出版社, 5-190. [Guo W X,Wen Z L,Liu J M,Zhao Z,Liu Z,Guo X J.2013. Jilin Oil Shale. Changchun: Jilin Science and Technology Press, 5-190] [9] 贺聪,吉利明,苏奥,刘颖,李剑锋,吴远东,张明震. 2017. 鄂尔多斯盆地南部延长组热水沉积作用与烃源岩发育的关系. 地学前缘, 24(6): 277-285. [He C,Ji L M,Su A,Liu Y,Li J F,Wu Y D,Zhang M X.2017. Relationship between hydrothermal sedimentation process and source rock development in the Yanchang Formation in southern Ordos Basin. Earth Science Frontiers, 24(6): 277-285] [10] 何红梅,徐德平,张香兰. 2002. 油页岩的开发与利用. 洁净煤技术, 8(2): 44-47. [He H M,Xu D P,Zhang X L.2002. Development and utilization of oil shale. Clean Coal Technology, 8(2): 44-47] [11] 侯读杰,王培荣,林壬子,李生杰. 1989. 茂名油页岩裂解气轻烃组成和热演化特征. 江汉石油学院学报, 11(4): 7-11. [Hou D J,Wang P R,Lin R Z,Li S J.1989. Light hydrocarbons in pyrolysis gas of Maoming oil shale and its thermal evolution signifcance. Journal of Jianghan Petroleum Institute, 11(4): 7-11] [12] 侯读杰,黄华清,黄福堂,孔庆云. 1999. 松辽盆地海侵地层的分子地球化学特征. 石油学报, 22(2): 30-34. [Hou D J,Huang H Q,Huang F T,Kong Q Y.1999. The characteristics of molecular geochemistry of marine transgression strata in Songliao Basin. Acta Petrolei Sinica, 22(2): 30-34] [13] 胡修棉. 2005. 白垩纪中期异常地质事件与全球变化. 地学前缘, 12(2): 222-230. [Hu X M.2005. Middle Cretaceous abnormal geological events and global change. Earth Science Frontiers, 12(2): 222-230] [14] 黄献好,孙玉琦,王伟超,刘炳强,张少林,张语涛,邵龙义. 2020. 柴北缘西大滩地区下—中侏罗统层序—古地理及聚煤特征. 沉积学报, 38(2): 266-283. [Huang X H,Sun Y Q,Wang W C,Liu B Q,Zhang S L,Zhang Y T,Shao L Y.2020. Sequence-palaeogeography and coal accumulation from the Early and Middle Jurassic in the Xidatan Area of the Northern Qaidam Basin. Acta Sedimentologica Sinica, 38(2): 266-283] [15] 贾建亮. 2012. 基于地球化学—地球物理的松辽盆地上白垩统油页岩识别与资源评价. 吉林大学博士论文: 24-162. [Jia J L.2012. Research on the recognition and resource evaluation of the Upper Cretaceous oil shale based on geochemistry-geophysics technique in the Songliao Basin(NE,China). Doctoral dissertation of Jilin University: 24-162] [16] 李殿超,朱建伟,严焕榕,郭敏,郑志文. 2006. 广东省茂名盆地油页岩的沉积特征及分布规律. 吉林大学学报(地球科学版), 36(6): 938-943. [Li D C,Zhu J W,Yan H R,Guo M,Zheng Z W.2006. Sedimentary characteristics and distribution rule of oil shale in Maoming Basin in Guangdong Province. Journal of Jilin University(Earth Science Edition), 36(6): 938-943] [17] 李术元,耿层层,钱家麟. 2014. 世界油页岩勘探开发加工利用现状: 并记2013年国外两次油页岩国际会议. 中外能源, 19(1): 25-33. [Li S Y,Geng C C,Qian J L.2014. Global oil shale exploration,development and utilization today: two Oil Shale Symposiums Held in 2013. Sino-Global Energy, 19(1): 25-33] [18] 李术元,何继来,侯吉礼,王薇,钱家麟. 2015. 世界油页岩勘探开发加工利用近况: 并记2014年国外两次油页岩国际会议. 中外能源, 20(1): 25-32. [Li S Y,He J L,Hou J L,Wang W,Qian J L.2015. Current status of the world's exploration and utilization of oil shale: a review of two Oil Shale International Symposiums held in 2014. Sino-Global Energy, 20(1): 25-32] [19] 李术元,钱家麟,秦匡宗,朱亚杰. 1986. 油页岩热解本征动力学的研究: 不同数学模型的计算结果. 石油学报(石油加工), 2(3): 1-10. [Li S Y,Qian J L,Qin K Z,Zhu Y J.1986. Study on intrinsic kinetics of oil shale pyrolysis: kinetic parameters determined by different models. Acta Petrolei Sinica(Petroleum Processing Section), 2(3): 1-10] [20] 李永红. 2018. 青海省侏罗系油页岩成矿模式研究. 中国煤炭地质, 30(7): 35-39. [Li Y H.2018. Study on Jurassic oil shale minerogenetic model in Qinghai. Coal Geology of China, 30(7): 35-39] [21] 李玉宏,武富礼. 2014. 陕西省铜川—黄陵地区三叠系油页岩及伴生油气资源. 北京: 地质出版社, 80-100. [Li Y H,Wu F L.2014. Triassic Oil Shale and Associated Oil and Gas Resources in Tongchuan Huangling Area,Shaanxi Province. Beijing: Geological Publishing House, 80-100] [22] 梁钰,侯读杰,张金川,杨光庆. 2014. 缺氧环境下热液活动对页岩有机质丰度的影响. 大庆石油地质与开发, 33(4): 158-165. [Liang Y,Hou D J,Zhang J C,Yang G Q.2014. Influences of the hydrothermal activities on the organic matter abundance of the shale in anoxic environment. Petroleum Geology & Oilfield Development in Daqing, 33(4): 158-165] [23] 刘立,王东坡. 1996. 湖相油页岩的沉积环境及其层序地层学意义. 石油试验地质, 18(3): 311-316. [Liu L,Wang D P.1996. Sedimentary environment of lacustrine oil shale and its sequence stratigraphic significance. Petroleum Geology & Experiment, 18(3): 311-316] [24] 柳蓉,刘招君,刘沣,孟庆涛,史冀忠,张健,杜江峰. 2008. 抚顺盆地始新世计军屯组油页岩贫富矿成矿机制. 大庆石油地质与开发, 27(2): 47-49,96. [Liu R,Liu Z J,Liu F,Meng Q T,Shi J Z,Zhang J,Du J F.2008. High grade and low grade oil shale metallogenic mechanism of Eocene Jijuntun Fomation in Fushun Basin. Petroleum Geology & Oilfield Development in Daqing, 27(2): 47-49,96] [25] 柳蓉,刘招君,杜江峰,刘冬青,杨小红,徐银波. 2012. 依兰盆地始新统达连河组油页岩成因新认识. 吉林大学学报(地球科学版), 42(4): 941-947. [Liu R,Liu Z J,Du J F,Liu D Q,Yang X H,Xu Y B.2012. New research on oil shale origin of Eocene Dalianhe Formation in Yilan Basin. Journal of Jilin University(Earth Science Edition), 42(4): 941-947] [26] 刘世忠,夏汉平,孔国辉,敖惠修,邓钊平,柯宏华,李丽华,谭鹏. 2002. 茂名北排油页岩废渣场的土壤与植被特性研究. 生态科学, 21(1): 25-28. [Liu S Z,Xia H P,Kong G H,Ao H X,Deng Z P,Ke H H,Li L H,Tan P.2002. The soil and vegetation of oil shale dump in Maoming city,Guangdong Province. Ecologic Science, 21(1): 25-28] [27] 刘招君,杨虎林,董清水,朱建伟,郭巍,叶松青,柳蓉,孟庆涛,张海龙,甘树才. 2009. 中国油页岩. 北京: 石油工业出版社, 3-280. [Liu Z J,Yang H L,Dong Q S,Zhu J W,Guo W,Ye S Q,Liu R,Meng Q T,Zhang H L,Gan S C.2009. Oil Shale in China. Beijing: Petroleum Industry Press, 3-280] [28] 刘招君,孙平昌,贾建亮,柳蓉,孟庆涛. 2011. 陆相深水环境层序识别标志及成因解释: 以松辽盆地青山口组为例. 地学前缘, 18(4): 171-180. [Liu Z J,Sun P C,Jia J L,Liu R,Meng Q T.2011. Distinguishing features and their genetic interpretation of stratigraphic sequences in continental deep water setting: A case from Qingshankou Formation in Songliao Basin. Earth Science Frontiers, 18(4): 171-180] [29] 刘招君,孙平昌,柳蓉,孟庆涛,胡菲. 2016a. 中国陆相盆地油页岩成因类型及矿床特征. 古地理学报, 18(4): 525-534. [Liu Z J,Sun P C,Liu R,Meng Q T,Hu F.2016a. Genetic types and deposit features of oil shale in continental basin in China. Journal of Palaeogeography(Chinese Edition), 18(4): 525-534] [30] 刘招君,孙平昌,柳蓉,孟庆涛,胡菲. 2016b. 敦密断裂带盆地群油页岩特征及成矿差异分析. 吉林大学学报(地球科学版), 46(4): 1090-1099. [Liu Z J,Sun P C,Liu R,Meng Q T,Hu F.2016b. Research on oil shale features and metallogenic differences in Dunhua-Mishan Fault Zone Basins. Journal of Jilin University(Earth Science Edition), 46(4): 1090-1099] [31] 刘志逊,代鸿章,张鑫刚,马腾,葛佐,贾音传. 2014. 依兰盆地达连河油页岩成矿控制因素研究. 地质科学, 49(4): 1232-1246. [Liu Z X,Dai H Z,Zhang X G,Ma T,Ge Z,Jia Y C.2014. Study on control factors of mineralization of oil shale in Dalianhe Formation,Yilan Basin. Chinese Journal of Geology, 49(4): 1232-1246] [32] 卢进才,李玉宏,魏仙样,魏建设. 2006. 鄂尔多斯盆地三叠系延长组长7油层组油页岩沉积环境与资源潜力研究. 吉林大学学报(地球科学版), 36(6): 928-932. [Lu J C,Li Y H,Wei X Y,Wei J S.2006. Research on the depositional environment and resources potential of the oil shale in the Chang 7 Member,Triassic Yanchang Formation in the Ordos Basin. Journal of Jilin University(Earth Science Edition), 36(6): 928-932] [33] 陆绍信,陈廷,沈志虹,王廷芬. 1990. 中国油页岩热性质研究: 油页岩的热膨胀性能. 石油学报(石油加工), 6(2): 95-99. [Lu S X,Chen T,Shen Z H,Wang T F.1990. Study on thermal properties of Chinese oil shales-the thermo-expansion of oil shales. Acta Petrolei Sinica(Petroleum Processing Section), 6(2): 95-99] [34] 罗佳强,沈忠民. 2005. 油页岩在渤海湾盆地济阳坳陷下第三系石油资源评价中的意义. 石油实验地质, 27(2): 164-168. [Luo J Q,Shen Z M.2005. Significance of oil shale in the Eogene petroleum resource evaluation of the Jiyang depression,the Bohaiwan basin. Petroleum Geology & Experiment, 27(2): 164-168] [35] 孟志勇. 2016. 四川盆地涪陵地区五峰组—龙马溪组含气页岩段纵向非均质性及其发育主控因素. 石油与天然气地质, 37(6): 838-846. [Meng Z Y.2016. Vertical heterogeneity and its controlling factors of the gas shale in the Wufeng-Longmaxi Fms in Fuling area,the Sichuan Basin. Oil & Gas Geology, 37(6): 838-846] [36] 钱家麟,尹亮. 2008. 油页岩—石油的补充能源. 北京: 中国石化出版社, 10-385. [Qian J L,Yin L.2008. Oil Shale-Supplement Energy for Oil. Beijing: China Petrochemical Press, 10-385] [37] 秦伯强,胡维平,陈伟民. 2004. 太湖水环境演化过程与机理. 北京: 科学出版社, 1-280. [Qin B Q,Hu W P,Chen W M.2004. Evolution Process and Mechanism of Taihu Lake Water Environment. Beijing: Science Press, 1-280] [38] 邱振,卢斌,陈振宏,张蓉,董大忠,王红岩,邱军利. 2019. 火山灰沉积与页岩有机质富集关系探讨: 以五峰组—龙马溪组含气页岩为例. 沉积学报, 37(6): 1296-1308. [Qiu Z,Lu B,Chen Z H,Zhang R,Dong D Z,Wang H Y,Qiu J L.2019. Discussion of the relationship between volcanic ash layers and organic enrichment of black shale: a case study of the Wufeng-Longmaxi gas shales in the Sichuan Basin. Acta Sedimentologica Sinica, 37(6): 1296-1308] [39] 邱振,邹才能. 2020. 非常规油气沉积学: 内涵与展望. 沉积学报, 38(1): 1-29. [Qiu Z,Zou C N.2020. Unconventional petroleum sedimentology: Connotation and Prospect. Acta Sedimentologica Sinica, 38(1): 1-29] [40] 任纪舜. 2005. 中国及邻区大地构图1:5000000. 北京: 地质出版社, 1-50. [Ren J S.2005. Composition of China and Its Adjacent Areas 1:5000000. Beijing: Geological Publishing House, 1-50] [41] 宋宇. 2017. 老黑山盆地下白垩统穆棱组油页岩与煤成矿机制的精细研究. 吉林大学博士论文, 1-148. [Song Y,2017. High resolution depiction of metallogenic mechanism in the Lower Cretaceous oil shale and coal of the Laoheishan Basin(NE China). Doctoral dissertation of Jilin University: 1-148] [42] 孙平昌,刘招君,孟庆涛,柳蓉,贾建亮,胡晓峰. 2011. 桦甸盆地古近纪充填特征及对油页岩成矿的影响. 煤炭学报, 36(7): 1110-1116. [Sun P C,Liu Z J,Meng Q T,Liu R,Jia J L,Hu X F.2011. Effect of the basin-fill features on oil shale formation in Paleogene,Huadian Basin. Journal of China Coal Society, 36(7): 1110-1116] [43] 孙平昌. 2013. 松辽盆地东南部上白垩统含油页岩系有机质富集环境动力学. 吉林大学博士论文: 98-189. [Sun P C.2013. Environmental dynamics of organic accumulation in the oil shale bearing layers in the Upper Cretaceous,Southeast Songliao Basin(NE China). Doctoral dissertation of Jilin University: 98-189] [44] 万晓樵,吴怀春,席党鹏,刘美羽,覃祚焕. 2017. 中国东北地区白垩纪温室时期陆相生物群与气候环境演化. 地学前缘, 24(1): 18-31. [Wan X Q,Wu H C,Xi D P,Liu M Y,Qin Z H.2017. Terrestrial biota and climate during Cretaceous greenhouse in NE China. Earth Science Frontiers, 24(1): 18-31] [45] 王东东,李增学,吕大炜,刘海燕,王平丽,冯婷婷. 2016. 陆相断陷盆地煤与油页岩共生组合及其层序地层特征. 地球科学, 41(3): 508-522. [Wang D D,Li Z X,Lü D W,Liu H Y,Wang P L,Feng T T.2016. Coal and oil shale paragenetic assemblage and sequence stratigraphic features in continental faulted basin. Earth Science, 41(3): 508-522] [46] 王东坡,刘招君,刘立. 1994. 松辽盆地演化与海平面升降. 北京: 地质出版社, 15-60. [Wang D P,Liu Z J,Liu L.1994. Evolution of Songliao Basin and Sea Level Change. Beijing: Geological Press, 15-60] [47] 王平丽,李增学,吕大炜,王真奉,刘海燕,王东东,冯婷婷. 2013. 典型盆地煤与油页岩共生成矿物质及古气候分析. 中国煤炭地质, 25(12): 8-11. [Wang P L,Li Z X,Lü D W,Wang Z F,Liu H Y,Wang D D,Feng T T.2013. Analysis on palaeoclimate and metallogenic materials of typical basins under co-occurring circumstances of coal and oil shale. Coal Geology of China, 25(12): 8-11] [48] 王贤清,张庆轩,钱家麟,朱亚杰. 1992. 颗粒油页岩燃烧及含硫杂质的转化. 燃料化学学报, 20(2): 50-57. [Wang X Q,Zhang Q X,Qian J L,Zhu Y J.1992. A study on combustion and sulfur transition of oil shale particle. Journal of Fuel Chemistry and Technology, 20(2): 50-57] [49] 王宇林,郭强,肖乾华,王威,杨春,魏恒飞,刘锦. 2009. 喀左盆地下白垩统九佛堂组油页岩特征及控矿条件. 吉林大学学报(地球科学版), 39(2): 211-216. [Wang Y L,Guo Q,Xiao Q H,Wang W,Yang C,Wei H F,Liu J.2009. Characteristic and ore-controlling condition of oil shale of Jiufotang Formation of Lower Cretaceous in Kazuo Basin. Journal of Jilin University(Earth Science Edition), 39(2): 211-216] [50] 席党鹏,万晓樵,冯志强,李顺,冯子辉,贾建忠,荆夏,司伟民. 2010. 松辽盆地晚白垩世有孔虫的发现: 来自松科1井湖海沟通的证据. 科学通报, 55(35): 3433-3436. [Xi D P,Wan X Q,Feng Z Q,Li S,Feng Z H,Jia J Z,Jing X,Si W M.2010. Discovery of Late Cretaceous foraminifera in the Songliao Basin: evidence from SK-1 and implications for identifying seawater incursions. Chinese Science Bulletin, 55(35): 3433-3436] [51] 谢尚克,王剑,付修根,杜佰伟. 2018. 西藏伦坡拉盆地丁青湖组油页岩特征及勘探有利区评价. 沉积与特提斯地质, 38(2): 55-63. [Xie S K,Wang J,Fu X G,Du B W.2018. Sedimentary characteristics of the oil shales from the Dingqinghu Formation and evaluation of favourable oil shale exploration areas in the Lunpola Basin,Xizang. Sedimentary Geology and Tethyan Geology, 38(2): 55-63] [52] 谢树成,殷鸿福,解习农,秦建中,史晓颖,胡超涌,颜佳新,黄俊华,周炼,杨香华,王永标,徐思煌,腾格尔. 2007. 地球生物学方法与海相优质烃源岩形成过程的正演和评价. 地球科学(中国地质大学学报), 32(6): 727-740. [Xie S C,Yin H F,Xie X N,Qin J Z,Shi X Y,Hu C Y,Yan J X,Huang J H,Zhou L,Yang X H,Wang Y B,Xu S H,Teng G E.2007. On the geobiological evaluation of hydrocarbon source rocks. Earth Science(Journal of China University of Geosciences), 32(6): 727-740] [53] 熊熠华. 2017. 山西省野西沟地区油页岩矿床地质特征及前景分析. 华北国土资源,(4): 63-65,69. [Xiong Y H.2017. Geological characteristics and prospect analysis of oil shale deposits in Yexigou Area,Shanxi Province. Huabei Land and Resources, (4): 63-65,69] [54] 许圣传,董清水,闫丽萍,于文斌,杜江峰,厚刚福. 2006. 山东黄县断陷盆地油页岩特征及生成机制. 吉林大学学报(地球科学版), 36(6): 954-958. [Xu S C,Dong Q S,Yan L P,Yu W B,Du J F,Hou G F.2006. The characteristics and the formation mechanism of the oil shale in Huangxian Faulted Basin,Shandong Province. Journal of Jilin University(Earth Science Edition), 36(6): 954-958] [55] 许圣传,刘招君,董清水,陈会军,柳蓉. 2012. 陆相盆地含煤、油页岩和蒸发盐地层单元沉积演化. 吉林大学学报(地球科学版), 42(2): 296-303. [Xu S C,Liu Z J,Dong Q S,Chen H J,Liu R.2012. Deposition and sedimentary evolution of coal,oil shale and evaporite-bearing strata in terrestrial basins. Journal of Jilin University(Earth Science Edition), 42(2): 296-303] [56] 徐学纯,邹海峰,孙友宏. 2016. 油页岩资源综合利用技术与应用. 长春: 吉林大学出版社, 10-35. [Xu X C,Zou H F,Sun Y H.2016. Comprehensive Utilization Technology and Application of Oil Shale Resources. Changchun: Jilin University Press, 10-35] [57] 徐银波,王君贤,刘招君,孟庆涛,宋宇,张家强,李锋. 2019. 老黑山盆地下白垩统穆棱组煤与油页岩共生特征与品质差异. 中国煤炭地质, 31(10): 27-32,58. [Xu Y B,Wang J X,Liu Z J,Meng Q T,Song Y,Zhang J Q,Li F.2019. Lower Cretaceous Muling Formation coal and oil Shale paragenetic features and quality differences in Laoheishan Basin.Coal Geology Of China, 31(10): 27-32,58] [58] 伊帆,朱利东,刘显凡,伊海生. 2016. 藏北羌塘盆地双湖地区下侏罗统油页岩的有机碳同位素异常和正构烷烃分布特征及大洋缺氧事件研究. 矿物学报, 36(3): 413-422. [Yi F,Zhu L D,Liu X F,Yin H S.2016. The distribution of n-alkanes and anomalies of organic carbon isotopes and the Toarcian Oceanic Anoxic Events of the Lower Jurassic oil shales in Qiangtang Basin,North Tibet,China. Acta Mineralogica Sinica, 36(3): 413-422] [59] 于海龙,姜秀民. 2001. 桦甸油页岩热解特性的研究. 燃料化学学报, 29(5): 450-453. [Yu H L,Jiang X M.2001. Study of pyrolysis of Huadian oil shale. Journal of Fuel Chemistry and Technology, 29(5): 450-453] [60] 于志强,彭平安,盛国英,傅家谟. 2000. 茂名与江汉第三系油页岩中生物标志物碳同位素研究. 科学通报,45(S1): 2783-2789. [Yu Z Q,Peng P A,Sheng G Y,Fu J M.2000. Carbon isotopes of biomarkers in tertiary oil shale of Maoming and Jianghan. Chinese Science Bulletin,45(S1): 2783-2789] [61] 袁伟,柳广弟,徐黎明,牛小兵. 2019. 鄂尔多斯盆地延长组7段有机质富集主控因素. 石油与天然气地质, 40(2): 326-334. [Yuan W,Liu G D,Xu L M,Niu X B.2019. Main controlling factors for organic matter enrichment in Chang 7 member of the Yanchang Formation,Ordos Basin. Oil & Gas Geology, 40(2): 326-334] [62] 张家强,刘志逊,钱家麟,刘招君. 2010. 中国发展油页岩产业的可行性. 北京: 地质出版社, 1-162. [Zhang J Q,Liu Z X,Qian J L,Liu Z J.2010. Feasibility of Developing Oil Shale Industry in China. Beijing: Geological Publishing House, 1-162] [63] 张水昌,张宝民,边立曾,金之钧,王大锐,张兴阳,高志勇,陈践发. 2005. 中国海相烃源岩发育控制因素. 地学前缘, 12(3): 39-48. [Zhang S C,Zhang B M,Bian L Z,Jin Z J,Wang D R,Zhang X Y,Gao Z Y,Chen J F.2005. Development constraints of marine source rocks in China. Earth Science Frontiers, 12(3): 39-48] [64] 张文正,杨华,解丽琴,杨奕华. 2010. 湖底热水活动及其对优质烃源岩发育的影响: 以鄂尔多斯盆地长 7烃源岩为例. 石油勘探与开发, 37(4): 424-429. [Zhang W Z,Yang H,Xie L Q,Yang Y H.2010. Lake-bottom hydrothermal activities and their influences on the high-quality source rock development: a case from Chang 7 source rocks in Ordos Basin. Petroleum Exploration and Development, 37(4): 424-429] [65] 赵隆业,陈基娘,王天顺. 1991a. 油页岩定义和煤、油页岩界限的讨论. 煤田地质与勘探, 13(1): 15-16,71. [Zhao L Y,Chen J N,Wang T S.1991a. Discussion on definition of oil shale and boundary of coal and oil shale. Coal Geology & Exploration, 13(1): 15-16,71] [66] 赵隆业,陈基娘,王天顺. 1991b. 关于中国油页岩的工业成因分类. 煤田地质与勘探, 19(5): 2-6. [Zhao L Y,Chen J N,Wang T S.1991b. Industrial-original classification of Chinese oil shales. Coal Geology & Exploration, 19(5): 2-6] [67] 周珍琦,董清水,厚刚福,许圣传,苗长盛. 2006. 与盐碱矿共生的油页岩形成环境及沉积演化: 以桐柏吴城盆地油页岩矿床为例. 吉林大学学报(地球科学版), 36(6): 1001-1005. [Zhou Z Q,Dong Q S,Hou G F,Xu S C,Miao C S.2006. The forming environment and sedimentary evolution of the oil shale intergrowthing with salt alkali mine with the oil shale deposit of Wucheng,Tongbai Basin as an example. Journal of Jilin University(Earth Science Edition), 36(6): 1001-1005] [68] 邹才能. 2014. 非常规油气地质学. 北京: 地质出版社. [Zou C N.2014. Unconventional Petroleum Geology. Beijing: Geological Publishing House] [69] 邹才能,潘松圻,赵群. 2020. 论中国“能源独立”战略的内涵、挑战及意义. 石油勘探与开发, 47(2): 1-11. [Zou C N,Pan S Q,Zhao Q.2020. On the connotation,challenge and significance of China's “energy independence” strategy. Petroleum Exploration and Development, 47(2): 1-11] [70] 邹艳荣,彭平安,宋之光,王成善. 2008. 白垩纪缺氧事件期间分子有机碳同位素偏移的2种不同机制. 地质学报, 82(1): 31-36. [Zou Y R,Peng P A,Song Z G,Wang C S.2008. The mechanism of stable carbon isotope excursion of the individual normal-alkane during the Cretaceous Oceanic Anoxic Event. Acta Geologica Sinica, 82(1): 31-36] [71] Bai Y Y,Liu Z J,Sun P C,Liu R,Hu X F,Zhou R J,Xu Y B,Zhao H Q,Wang J P.2017. Diverse sedimentary conditions during deposition of coal and oil shale from the Meihe Basin(Eocene,Ne China). Journal of Sedimentary Research, 87(10): 1100-1120. [72] Bechtel A,Jia J L,Strobl S A I,Sachsenhofer R F,Liu Z J,Gratzer R,Püttmann W.2012. Paleoenvironmental conditions during deposition of the Upper Cretaceous oil shale sequences in the Songliao Basin(NE China): Implications from geochemical analyses. Organic Geochemistry, 46(5): 76-95. [73] Bohacs K M,Carroll A R,Neal J E,Mankiewicz P J.2000. Lake-basin type,source potential,and hydrocarbon character: an integrated sequence-stratigraphic geochemical framework.AAPG Studies in Geology, 46: 3-34. [74] Boucot A J,Gray J.2001. A critique of Phanerozoic climatic modes involving changes in the CO2 content of the atmosphere. Earth Science Reviews, 56: 1-159. [75] Cao H S,Kaufman A J.,Shan X L,Cui H,Zhang G J.2016. Sulfur isotope constraints on marine transgression in the lacustrine Upper Cretaceous Songliao Basin,Northeastern China. Palaeogeography, Palaeoclimatology, Palaeoecology,451: 152-163. [76] Carroll A R,Bohacs K M.1999. Stratigraphic classification of ancient lakes: Balancing tectonic and climatic controls. Geology,27(2):99-102. [77] Carroll A R,Bohacs K M.2001. Lake type controls on petroleum source rock potential in nonmarine basins. AAPG Bulletin, 85(6): 1033-1053. [78] Carroll A R.1998. Upper Permian lacustrine organic facies evolution,Southern Junggar Basin,NW China. Organic Geochemistry, 28(11): 649-667. [79] Dean W E,Claypool G E,Thide J.1984. Accumulation of organic matter in Cretaceous oxygen-deficient depositional environments in the central Pacific Ocean. Organic Geochemistry, 7(1): 1-51. [80] Emiliani C,Rooth C,Stipp J J.1978. The late Wisconsin flood into the Gulf of Mexico. Earth and Planetary Science Letters, 41: 159-162. [81] Feng Z Q,Jia C Z,Xie X N,Zhang S,Feng Z H,Cross T A.2010. Tectonostratigraphic units and stratigraphic sequences of the nonmarine Songliao basin,northeast China. Basin Research, 22: 79-95. [82] Frogner P,Gíslason S R,Óskarsson N.2001. Fertilizing potential of volcanic ash in ocean surface water. Geology, 29(6): 487-490. [83] Haq B U,Hardenbol J,Vail P R.1987. Chronology of fluctuating sea levels since the Triassic(250 million years ago to present). Science,235:1156-1167. [84] He H,Deng C,Wang P,Pan Y,Zhu R.2012. Toward age determination of the termination of the Cretaceous Normal Superchron. Geochemistry, Geophysics, Geosystems,13(2):1-20. [85] Jenkyns H C,Skelton P W,Spicer R A, Kelley S P, Gilmour I.2003. The Cretaceous World. New York: Cambridge University Press. [86] Sheridan R E,Larson R L.1992. Geological consequences of superplumes. Geology, 20(5): 477. [87] Jeppesen E,Meerhoff M,Jacobsen B A,Hansen R S,Søndergaard M,Jensen J P,Lauridsen T L,Mazzeo N,Branco C W C.2007. Restoration of shallow lakes by nutrient control and biomanipulation-the successful strategy varies with lake size and climate. Hydrobiologia,581(1):269-285. [88] Leckie R M,Bralower T J,Cashman R.2002. Oceanic anoxic events and plankton evolution: Biotic response to tectonic forcing during the Mid-Cretaceous. Paleoceanography, 17(3): 1-29. [89] Li Y J,Sun P C,Liu Z J,Wang J X,Li Y,Zhang M Q.2019. Lake level controls on oil shale distribution in the Lucaogou Formation,Wujiawan Area,Junggar Basin,Northwest China. Energy & Fuels, 33: 8383-8393. [90] Lü D W,Wang D D,Li Z X,Liu H Y,Li Y.2017. Depositional environment,sequence stratigraphy and sedimentary mineralization mechanism in the coal bed-and oil shale-bearing succession: a case from the Paleogene Huangxian Basin of China. Journal of Petroleum Science and Engineering, 148: 32-51. [91] Meng Q T,Bechtel A,Sachsenhofer R F,Liu Z J,Gross D,Sun PC,Hu F,Li L,Wang K B,Xu C,Chen L L,Zeng W R.2019. Hydrocarbon potential and palaeo-depositional environment of lacustrine source rocks: middle Jurassic Shimengou Formation,northern Qaidam basin,NW China. Journal of Petroleum Geology,42(1):37-58. [92] Miller K G,Kominz M A,Browning J V,Wright J D,Mountain G S,Katz M E,Sugarman P J,Cramer B S,Christie-Blick N,Pekar S F.2005. The Phanerozoic record of global sea-level change. Science, 310: 323-326. [93] Passey Q R,Creaney S,Kulla J B,Creaney S,Stroud. 1990. A practical model for organic richness from porosity and resistivity logs. AAPG Bulletin, 74(12): 1777-1794. [94] Peters K E,Snedden J W,Sulaeman A,Sarg J F,Enrico R J.2000. A new geochemical-sequence stratigraphic model for the Mahakam delta and Makassar slope,Kalimantan,Indonesia. AAPG Bulletin, 84(1): 3-34. [95] Robinson S A,Aandrews J E,Hesselbo S P,Radley J D,Dennis P F,Harding I C,Allen P.2002. Atmospheric pCO2 and depositional environment from stable-isotope geochemistry of calcrete nodules(Barremian,Lower Cretaceous,Wealden Beds,England). Journal of the Geological Society,London, 159: 215-224. [96] Sahagian D L.1993. Structural evolution of African basins: stratigraphic synthesis. Basin Research,5(1):41-54. [97] Song Y,Liu Z J,Bechtel A,Sachsenhofer R F,Groß D,Meng Q T.2017. Paleoenvironmental reconstruction of the coal-and oil shale-bearing interval in the Lower Cretaceous Muling Formation,Laoheishan Basin,Northeast China. International Journal of Coal Geology,172:1-18. [98] Strobl S A I,Sachsenhofer R F,Bechtel A,Meng Q T,Sun P C.2015. Deposition of coal and oil shale in NE China: the Eocene Huadian Basin compared to the coeval Fushun Basin. Marine & Petroleum Geology,64:347-362. [99] Strobl S A I,Sachsenhofer R F,Bechtel A,Gratzer R,Gross D,Bokhari S N H,Liu R,Liu Z J,Meng Q T,Sun P C.2014. Depositional environment of oil shale within the Eocene Jijuntun Formation in the Fushun Basin(NE China). Marine & Petroleum Geology,56:166-183. [100] Sun P C,Liu Z J,Bai Y Y,Xu Y B,Liu R,Meng Q T,Hu F.2016. Accumulation stages and evolution characteristics of oil shale and coal in the Dunhua-Mishan Fault Zone,Northeast China. Oil Shale, 33(3): 203-215. [101] Sun P C,Sachsenhofer R F,Liu Z J,Strobl S A I,Meng Q T,Liu R,Zhen Z.2013. Organic matter accumulation in the oil shale-and coal bearing Huadian Basin(Eocene;NE China).International Journal of Coal Geology, 105: 1-15. [102] Sun Y H,Bai FT,Lü X S,Li Q,Liu Y M,Guo M Y,Guo W,Liu B C.2015. A novel energy-efficient pyrolysis process: self-pyrolysis of oil shale triggered by topochemical heat in a horizontal fixed bed. Sci Rep, 5(8290): 1-8. [103] Tao S,Tang D Z,Xu H,Liang J L, Shi, X F.2013. Organic geochemistry and elements distribution in Dahuangshan Oil Shale,Southern Junggar Basin: origin of organic matter and depositional environment. International Journal of Coal Geology,115:41-51. [104] Vail P R,Mitchum Jr.R M,Thompson S. 1977. Seismic stratigraphy and global changes of sea level. In: Payton C E(ed).Seismic Stratigraphy-Applications to Hydrocarbon Exploration. AAPG Memoir, 26: 83-97. [105] Wang C S,Scott R W,Wan XQ,Graham S A,Huang Y J,Wang P J,Wu H C,Dean W E,Zhang L M.2013. Late Cretaceous climate changes recorded in Eastern Asian lacustrine deposits and North American Epieric sea strata. Earth-Science Reviews,126:275-299. [106] Wang J X,Sun P C,Liu Z J,Li L.2020. Source Depositional environmental controls on the genesis and characteristics of oil shale: case study of the Middle Jurassic Shimengou Formation,northern Qaidam Basin,Northwest China. Geological Journal, 55(6): 4585-4603. [107] Watts A B,Steckler M S.1979. Subsidence and eustasy at the continental margin of Eastern North America. In: Talwani M,Hay W W,Ryan W B F(eds). Deep drilling results in the Atlantic Ocean: Continental Margins and Paleoenvironment. AGU Maurice Ewing ser., 3: 218-234. [108] Weissert H,Erba E.2004. Volcanism,CO2 and palaeoclimate: a Late Jurassic Early Cretaceous carbon and oxygen isotope record. Journal of the Geological Society,London, 161: 695-702. [109] Xu J J,Liu Z J,Bechtel A,Sachsenhofer R F,Jia J L,Meng Q T,Sun P C.2019. Organic matter accumulation in the Upper Cretaceous Qingshankou and Nenjiang Formations,Songliao Basin(NE China): implications from high-resolution geochemical analysis. Marine and Petroleum Geology, 102: 187-201. [110] Xu Y B,Sun P C,Yao S Q,Liu Z J,Tian X M,Li F,Zhang J Q.2019. Progress in exploration,development and utilization of oil shale in China. Oil Shale, 36(2): 285-304. [111] Zhang P L,Meng Q T,Liu Z J,Hu F,Xue M.2020a. A comparative study of oil shale-bearing intervals in the Lower Cretaceous Jiufotang Formation in the Beipiao Basin,Northeast China based on sedimentary organic facies theory. Oil Shale, 37(1): 32-50. [112] Zhang K,Liu R,Liu Z J,Li B L,Han J B,Zhao K A.2020b. Influence of volcanic and hydrothermal activity on organic matter enrichment in the Upper Triassic Yanchang Formation,southern Ordos Basin,Central China. Marine and Petroleum Geology, 112: 104059. DOI: 10.1016/j.marpetgeo.2019.104059. [113] Zhao J M.2017. Method and Process for Extracting Shale Oil and Gas by Fracturing and Chemical Retorting in Oil Shale In-Situ Horizontal Well. U.S. Patent. 9,784, 086, B2. [114] Zhao X X.2005. The Earth's magnetic field and global geologic phenomena in mid-Cretaceous. Earth Science Frontiers, 12(2): 199-216.