Development characteristics of volcanic tuff of the Wufeng-Longmaxi Formations in Xianfeng area of western Hubei and its influence on enrichment of organic matter in shale
LUO Fan1, DUAN Ke1,3, ZHANG Hao2, XU Lulu1, WANG Yi1, CHEN Wei1, YANG Jie1
1 Hubei Geological Survey,Wuhan 430034,China; 2 Hubei Coal Geological Exploration Institute,Wuhan 430070,China; 3 Key Laboratory of Paleontology and Geological Environment Evolution of Hubei Province,Wuhan 430205,China
Abstract The organic-rich shale of Wufeng Formation and Longmaxi Formation in Xianfeng area of western Hubei Province contains multilayer volcanic tuff,but the internal relationship between volcanic activity and organic matter enrichment in marine shels has not been systematically studied. Based on the core and outcrop data of Well XY 1 in Xianfeng area,the organic-rich mud shale and volcanic tuff of Wufeng-Longmaxi Formations were systematically sampled,rock and ore identification,trace element,rare earth element and organic carbon content(TOC)tests were carried out,and the distribution characteristics,source rock composition,tectonic setting and genetic mechanism of volcanic tuff of Wufeng-Longmaxi Formations were expounded. The volcanic activity in this sedimentary period and its influence on the enrichment of organic matter in shale are discussed. The results show that the Wufeng-Longmaxi Formations can be divided into dense,sub-dense and undeveloped tuff segments. The primary magmatic properties of the tuff were mainly neutral andesite,and the volcanic ash originates from the volcanic eruption event of the island arc formed by the collision between the northern margin of the Yangtze and the ancient Qinling Ocean. Volcanic ash was an important material source in the Middle Yangtze Retention Basin where terrigenous detritus supply was insufficient in Late Ordovician and Early Silurian. On one hand,volcanic ash provided abundant nutrients for the growth of marine microorganisms and improved the marine palaeoproductivity. On the other hand,volcanism promoted the formation of anoxic environment in the ocean,which was conducive to the burial and preservation of organic matter. The results can provide basic geological data for further exploration of shale gas in the Wufeng-Longmaxi Formations in western Hubei Province.
Fund:“The investigation and evaluation of middle-shallow shale gas resource potential in western Hubei” Project of Hubei Geological Bureau(No.KCDZ2024-34)and the Open Research Fund of the Key Laboratory of Paleontology and Geoenvironmental Evolution of Hubei Province(编号: PEL-202005)
Corresponding Authors:
DUAN Ke,born in 1989,is a senior engineer. He is mainly engaged in shale gas geological investigation and research. E-mail: 359597913@qq.com. ZHANG Hao,born in 1989,is a senior engineer. He is mainly engaged in basic geology,mineral geology,oil and gas geology.E-mail: zhang_haocug@163.com.
About author: LUO Fan,born in 1988,is an engineer with his masteral degree. He is mainly engaged in basic geology and shale gas geological survey. E-mail: 179961510@qq.com.
Cite this article:
LUO Fan,DUAN Ke,ZHANG Hao et al. Development characteristics of volcanic tuff of the Wufeng-Longmaxi Formations in Xianfeng area of western Hubei and its influence on enrichment of organic matter in shale[J]. JOPC, 2024, 26(5): 1058-1071.
LUO Fan,DUAN Ke,ZHANG Hao et al. Development characteristics of volcanic tuff of the Wufeng-Longmaxi Formations in Xianfeng area of western Hubei and its influence on enrichment of organic matter in shale[J]. JOPC, 2024, 26(5): 1058-1071.
[1] 邓卜铭. 2023. 川南五峰—龙马溪组页岩的硅质成因分析. 石化技术,30(2): 155-157. [Deng B M.2023. Genetic analysis of siliceous shale in Wufeng-Longmaxi Formation,southern Sichuan. Petrochemical Technology,30(2): 155-157] [2] 葛祥英. 2020. 四川盆地东部奥陶—志留纪交替时期事件沉积与有机质富集. 中国地质大学(北京)博士学位论文. [Ge X Y.2020. Event deposition and organic matter enrichment during Ordovician Silurian alternations in eastern Sichuan Basin. Doctoral dissertation of China University of Geosciences(Beijing)] [3] 葛祥英,牟传龙,余谦,刘伟,门欣,何江林,郑斌嵩,梁薇. 2021. 四川盆地东部五峰组—龙马溪组黑色页岩有机质富集规律探讨. 沉积与特提斯地质,41(3): 418-435. [Ge X Y,Mou C L,Yu Q,Liu W,Men X,He J L,Zheng B S,Liang W.2021. Organic matter enrichment in black shale of Wufeng-Longmaxi Formation,eastern Sichuan Basin. Sedimentary and Tethian Geology,41(3): 418-435] [4] 胡艳华,刘健,周明忠,汪方跃,丁兴,凌明星,孙卫东. 2009a. 奥陶纪和志留纪钾质斑脱岩研究评述. 地球化学,38(4): 393-404. [Hu Y H,Liu J,Zhou M Z,Wang F Y,Ding X,Ling M X,Sun W D.2009a. A review on the study of Ordovician and Silurian potassic porphyry. Geochemistry,38(4): 393-404] [5] 胡艳华,孙卫东,丁兴,汪方跃,凌明星,刘健. 2009b. 奥陶纪—志留纪边界附近火山活动记录: 来华南周缘钾质斑脱岩的信息. 岩石学报,25(12): 3298-3308. [Hu Y H,Sun W D,Ding X,Wang F Y,Ling M X,Liu J.2009b. Volcanic activity records near the Ordovician-Silurian boundary: information on the potassic porphyry in the periphery of South China. Acta Petrologica Sinica,25(12): 3298-3308] [6] 韩载华,赵靖舟,孟选刚,沈振振,杨荣国,张恒,高飞龙. 2020. 鄂尔多斯盆地三叠纪湖盆东部“边缘”长7段烃源岩的发现及其地球化学特征. 石油实验地质,42(6): 991-1000. [Han Z H,Zhao J Z,Meng X G,Shen Z Z,Yang R G,Zhang H,Gao F L.2020. Discovery and geochemical characteristics of source rocks in Chang 7 Member of the eastern “margin” of the Triassic lake Basin,Ordos Basin. Petroleum Geology & Experiment,42(6): 991-1000] [7] 何龙,王云鹏,陈多福,王钦贤,王成. 2019. 重庆南川地区五峰组—龙马溪组黑色页岩沉积环境与有机质富集关系. 天然气地球科学,30(2): 203-218. [He L,Wang Y P,Chen D F,Wang Q X,Wang C.2019. Relationship between sedimentary environment and organic matter enrichment of black shale in Wufeng-Longmaxi Formation,Nanchuan area,Chongqing. Natural Gas Geoscience,30(2): 203-218] [8] 牟传龙,葛祥英,许效松,周恳恳,梁薇,王秀平. 2014. 中上扬子地区晚奥陶世岩相古地理及其油气地质意义. 古地理学报,16(4): 427-440. [Mou C L,Ge X Y,Xu X S,Zhou K K,Liang W,Wang X P.2014. Late Ordovician lithofacies paleogeography and its oil-gas geological significance in the Middle and Upper Yangtze region. Journal of Palaeogeography(Chinese Edition),16(4): 427-440] [9] 牟传龙,王秀平,王启宇,周恳恳,梁薇. 2016. 川南及邻区下志留统龙马溪组下段沉积相与页岩气地质条件的关系. 古地理学报,18(3): 457-472. [Mou C L,Wang X P,Wang Q Y,Zhou K K,Liang W.2016. Relationship between sedimentary facies and shale gas geological conditions of Lower Silurian Longmaxi Formation in southern Sichuan and adjacent areas. Journal of Palaeogeography(Chinese Edition),18(3): 457-472] [10] 聂海宽,金之钧,马鑫,刘忠宝,林柘,杨振恒. 2017. 四川盆地及邻区上奥陶统五峰组—下志留统龙马溪组底部笔石带及沉积特征. 石油学报,38(2): 160-174. [Nie H K,Jin Z J,Ma X,Liu Z B,Lin T,Yang Z H.2017. Graptolite belt and sedimentary characteristics of Upper Ordovician Wufeng Formation and Lower Silurian Longmaxi Formation in Sichuan Basin and adjacent areas. Acta Petrolei Sinica,38(2): 160-174] [11] 舒良树. 2012. 华南构造演化的基本特征. 地质通报,31(7): 1035-1053. [Shu L S.2012. Basic characteristics of tectonic evolution in South China. Geological Bulletin of China,31(7): 1035-1053] [12] 王书荣,宋到福,何登发. 2013. 三塘湖盆地火山灰对沉积有机质的富集效应及凝灰质烃源岩发育模式. 石油学报,34(6): 1077-1087. [Wang S R,Song D F,He D F.2013. Enrichment effect of volcanic ash on sedimentary organic matter and development model of tuffaceous source rock in Santanghu Basin. Acta Petrolei Sinica,34(6): 1077-1087] [13] 王玉满,李新景,陈波,韩京,张家铭,袁飞,马杰,代兵,王浩,蒋珊. 2018. 中上扬子地区埃隆阶最厚斑脱岩层分布特征及地质意义. 天然气地球科学,29(1): 42-54. [Wang Y M,Li X J,Chen B,Han J,Zhang J M,Yuan F,Ma J,Dai B,Wang H,Jiang S.2018. Distribution characteristics and geological significance of the thickest porphyroclastic strata of Ellonian stage in the middle and upper Yangtze region. Natural Gas Geoscience,29(1): 42-54] [14] 王玉满,李新景,王皓,蒋珊,陈波,马杰,代兵. 2019. 四川盆地东部上奥陶统五峰组—下志留统龙马溪组斑脱岩发育特征及地质意义. 石油勘探与开发,46(4): 653-665. [Wang Y M,Li X J,Wang H,Jiang S,Chen B,Ma J,Dai B.2019. Development characteristics and geological significance of porphyry in Upper Ordovician Wufeng Formation and Lower Silurian Longmaxi Formation,eastern Sichuan Basin. Petroleum Exploration and Development,46(4): 653-665] [15] 谢浩然,梁超,吴靖,籍士超. 2023. 火山活动对沉积古环境及有机质富集的影响. 古地理学报,25(4): 768-787. [Xie H R,Liang C,Wu J,Ji S C.2019. Effects of volcanic activity on sedimentary palaeoenvironment and organic matter enrichment. Journal of Palaeogeography(Chinese Edition),25(4): 768-787] [16] 谢尚克,汪正江,王剑,卓皆文. 2012. 湖南桃源郝坪奥陶系五峰组顶部火山凝灰岩LA-ICP-MS锆石U-Pb年龄. 沉积与特提斯地质,32(4): 65-69. [Xie S K,Wang Z J,Wang J,Zhuo J W.2012. LA-ICP-MS Zircon U-Pb age of volcanic tuff at the top of Ordovician Wufeng Formation,Taoyuan,Hunan Province. Sedimentation and Tethys Geology,32(4): 65-69] [17] 熊国庆,王剑,李园园,余谦,门玉澎,周小琳,熊小辉,周业鑫,杨潇. 2019. 南大巴山东段上奥陶统五峰组—下志留统龙马溪组钾质斑脱岩锆石U-Pb年龄及其构造意义. 地质学报,93(4): 843-864. [Xiong G Q,Wang J,Li Y Y,Yu Q,Men Y P,Zhou X L,Xiong X H,Zhou Y X,Yang X.2019. Zircon U-Pb age of Upper Ordovician Wufeng Formation and Lower Silurian Longmaxi Formation potassic porphyry in the eastern part of the Southern Daba Mountains and its tectonic significance. Acta Geologica Sinica,93(4): 843-864] [18] 许露露,温雅茹,周向辉,居字龙,陈威,杨洁,任志军,文建航. 2022. 鄂西黄陵背斜南缘下寒武统牛蹄塘组一段古沉积环境演化特征: 以秭地1井为例. 石油实验地质,44(3): 456-465. [Xu L L,Wen Y R,Zhou X H,Ju Z L,Chen W,Yang J,Ren Z J,Wen J H.2022. Paleosedimentary environment evolution characteristics of the first member of the Lower Cambrian Niutitang Formation,southern margin of Huangling anticline,western Hubei: a case study of well ZD1. Petroleum Geology & Experiment,44(3): 456-465] [19] 郑爱维,孟志勇,李凯,刘莉,柳筠,彭国红,易雨昊,蔡进. 2023. 川东红星地区二叠系吴家坪组页岩储层纵向非均质性特征及其发育主控因素. 天然气地球科学,34(9): 1500-1514. [Zheng A W,Meng Z Y,Li K,Liu L,Liu J,Peng G H,Yi Y H,Cai J.2023. Longitudinal heterogeneity of Permian Wujiaping Formation shale reservoir in Hongxing area,eastern Sichuan and its main controlling factors. Natural Gas Geoscience,34(9): 1500-1514] [20] 周明忠,罗泰义,黄智龙,龙汉生,杨勇. 2007. 钾质斑脱岩的研究进展. 矿物学报,27(3-4): 351-359. [Zhou M Z,Luo T Y,Huang Z L,Long H S,Yang Y.2007. Research progress of potassic porphyry. Acta Minerologica Sinica,27(3-4): 351-359] [21] 周国晓,魏国齐,胡国艺,武赛军,田亚杰,董才源. 2020. 四川盆地早寒武世裂陷槽西部页岩发育背景与有机质富集. 天然气地球科学,31(4): 498-506. [Zhou G X,Wei G Q,Hu G Y,Wu S J,Tian Y J,Dong C Y.2020. Shale development background and organic matter enrichment in western Early Cambrian rift trough,Sichuan Basin. Natural Gas Geoscience,31(4): 498-506] [22] Du X B,Jia J X,Zhao K,Shi J C,Shu Y,Liu Z H,Duan D.2021. Was the volcanism during the Ordovician: Silurian transition in South China actually global in extent?Evidence from the distribution of volcanic ash beds in black shales. Marine and Petroleum Geology,123: 104721. [23] Duggen S,Croot P,Schacht U,Hoffmann L.2007. Subduction zone volcanic ash can fertilize the surface ocean and stimulate phytoplankton growth: evidence from biogeochemical experiments and satellite data. Geophysical Research Letters,34(1): L01612. [24] Floyd P A, Leveridge B E.1987. Tectonic environment of the Devonian Gramscatho Basin, South Cornwall:framework mode and geochemical evidence from turbiditic sandstones. Journal of the Geological Society, 144(4):531-542. [25] Pearce J A,Norry M J.1979. Petrogenefie implications of Ti,Zr,Y and Nb variations in volcanic rocks. Contributions to Mineralogy and Petrology,69(1): 33-47. [26] Pearce J A,Peate D W.1995. Tectonic implications of the composition of volcanic arc magmas. Annual Review of Earth and Planetary Sciences,23(1): 251-286. [27] Pearce J A,Harris N B W,Tindle A G.1984. Trace element discrimination diagrams for the tectonic interpretation of granitic rocks. Journal of Petrology,25(4): 956-983. [28] Ross D J K,Bustin R M.2009. Investigating the use of sedimentary geochemical proxies for paleoenvironment interpretation of thermally mature organic-rich strata: examples from the Devonian-Mississippian shales,Western Canadian Sedimentary Basin. Chemical Geology,260(1/2): 1-19. [29] Shen J,Algeo T J,Hu Q,Zhang N,Zhou L,Xia W C,Xie S C,Feng Q L.2012. Negative C-isotope excursions at the Permian-Triassic boundary linked to volcanism. Geology,40(11): 963-966. [30] Su W B,Huff W D,Ettensohn F R,Liu X M,Zhang J E,Li Z M.2009. Kbentonite,black-shale and flysch successions at the Ordovician: Silurian transition,South China: possible sedimentary responses to the accretion of Cathaysia to the Yangtze Block and its implications for the evolution of Gondwana. Gondwana Research,15(1): 111-130. [31] Tribovillard N,Algeo T J,Lyons T,Riboulleau A.2006. Trace metals as paleoredox and paleoproductivity proxies: an update. Chemical Geology,232(1/2): 12-32. [32] Winchester J A,Floyd P A.1977. Geochemical discrimination of different magma series and their differentiation products using immobile elements. Chemical Geology,20(4): 325-343. [33] Xu L L,Huang S P,Wang Y,Zhou X H,Liu Z X,Wen Y R,Zhang Y L,Sun M D.2023. Palaeoenvironment evolution and organic matter enrichment mechanisms of the Wufeng-Longmaxi shales of Yuan’an block in western Hubei,middle Yangtze: implications for shale gas accumulation potential. Marine and Petroleum Geology,152:106242. [34] Yang S C,Hu W X,Wang X L,Jiang B Y,Yao S P,Sun F N,Huang Z C,Zhu F.2019. Duration,evolution,and implications of volcanic activity across the Ordovician Silurian transition in the Lower Yangtze region,South China. Earth and Planetary Science Letters,518: 13-25.