Abstract:Helan Mountain-Liupan Mountain area is the key location to study the tectonic background in the west of North China Plate. We collected 20 samples of mud stone and silty mud stone and 1 coal sample in the study area. Then the testing on major,trace and rare earth elements were carried out by bulk rock analysis and ICP-MS,which could help understand the geochemistry characteristics of these samples. The results show: The ratio value of Al2O3/SiO2 stays steady from 0.17 to 0.31 with the average value 0.25; the ratio value of K2O/Na2O has a big fluctuation from 0.77 to 73.77 with the average value 9.78; the ratio of Al2O3/(Na2O+CaO)ranges from 0.49 to 96 with the average value 15.68. These ratio values are related to compositional maturity,element migration,hydrothermal fluid and weathering. Strong correlation among some elements is a natural advantage to determine provenance area. The total content of rare earth elements in the fine clastic sediments changes rapidly from 132.16×10μg·g-1 to 394.47μg·g-1 with the average value 198.68 μg·g-1. Meanwhile chondrite-normalized REE patterns reveal a deficit of light rare earth elements while the enriched heavy ones,negative Eu anomal and weak Ce anomaly. All of these characteristics together with UCC normalized REE patterns,ratios of La/Yb,Gd/Yb,La/Th and Hf indicate that the major source rock is felsic rock with slight elder sedimentary rock and basic rock or special minerals,meanwhile, the post ̄Archeozoic strata provided most source rocks. The tectonic discrimination diagrams of trace element show the provenance of Middle Jurassic is close to the continental island arc and active continental margin,Mongol-Hinggan and Qilian orogenic belt maybe the provenance of the study area. The ratios of CIA and A-CN-K plots reflect the source rocks had experienced strong weathering with varying degrees in various regions.
Luo Wei,Liu Chiyang,Zhang Dongdong et al. Geochemistry characteristics of the Middle Jurassic Zhiluo Formation in Helan Mountain-Liupan Mountain area and their geological significances[J]. JOPC, 2016, 18(6): 1030-1043.
[1] 白云来,王新民,刘化清,李天顺. 2006. 鄂尔多斯盆地西部边界的确定及其地球动力学背景. 地质学报,80(6): 792-813. [Bai Y L,Wang X M,Liu H Q,Li T S. 2006. Determination of the borderline of the western Ordos Basin and its geodynamics background. Acta Geologica Sinica,80(6): 792-813] [2] 高志友. 2005. 南海表层沉积物地球化学特征及物源指示. 成都理工大学博士学位论文. [Gao Z Y. 2005. The geochemical characteristics and provenance of the surface sediment in South China Sea. Doctoral Dissertation of Chengdu University of Technology] [3] 胡俊杰,李琦,方念乔,杨静懿,黄静,陈若瑜. 2014. 藏北羌塘盆地中央隆起带下二叠统展金组沉积岩稀土元素地球化学特征及其地质意义. 古地理学报,16(6): 926-934. [Hu J J,Li Q,Fang N Q,Yang J Y,Huang J,Chen R Y. 2014. REE geochemical characteristics and geological significance of sedimentary rocks of the Lower Permian Zhanjin Formation in central uplift zone of Qiangtang Basin,northern Tibet Plateau. Journal of Palaeogeography(Chinese Edition),16(6): 926-934] [4] 黄汝昌. 1982. 陆相沉积中古气候演变及元素的迁移、聚集和演化. 见: 中国科学院兰州地质研究所编. 中国科学院兰州地质研究所集刊. 北京: 科学出版社. 12-18. [Huang R C. 1982. Paleoclimate evolution and elements transfer,assemblage and evolution in terrestrial sediments. In: Lanzhou Geology Research Institute,Chinese Academy of Sciences (ed). Collection of Lanzhou Geology Research Institute,Chinese Academy of Sciences. Beijing: Science Press, 12-18] [5] 贾恒,李保侠,荆国强. 2012. 鄂尔多斯盆地西缘惠安堡地区构造地质及铀成矿特征. 铀矿地质,28(3): 148-151,186. [Jia H,Li B X,Jing G Q. 2012. Structural geology and mineralization of Uranium Deposits in the Huianpu Area,West of Ordos Basin. Uranium Geology,28(3): 148-151,186] [6] 李大华,陈坤,邓涛,程方平,杨洁. 2002. 中国西南地区煤中砷的分布及富集因素探讨. 中国矿业大学学报,31(4): 419-422. [Li D H,Chen K,Deng T,Cheng F P,Yang J. 2002. Distribution and enrichment factors of Arsenic in coals of Southwestern China. Journal of China University of Mining & Technology,31(4): 419-422] [7] 刘池洋,赵红格,桂小军,岳乐平,赵峻峰,王建强. 2006. 鄂尔多斯盆地演化—改造的时空坐标及其成藏(矿)响应. 地质学报,80(5): 617-638. [Liu C Y,Zhao H G,Gui X J,Yue L P,Zhao J F,Wang J Q. 2006. Space-Time coordinate of the evolution and reformation and mineralization response in Ordos Basin. Acta Geologica Sinica,80(5): 617-638] [8] 刘池洋,赵红格,王锋,陈洪. 2005. 鄂尔多斯盆地西缘(部)中生代构造属性. 地质学报,79(6): 737-747. [Liu C Y,Zhao H G,Wang F,Chen H. 2005. Attributes of the Mesozoic structure on the west margin of the Ordos Basin. Acta Geologica Sinica,79(6): 737-747] [9] 罗伟,刘池洋,张东东,王建强,郭配,牛海青,赵岩,王飞飞. 2015. 鄂尔多斯盆地西缘石岗沟地区直罗组碎屑锆石LA-ICP-MS U-Pb年代学特征及物源区判定. 矿物岩石,35(4): 106-115. [Luo W,Liu C Y,Zhang D D,Wang J Q,Guo P,Niu H Q,Zhao Y,Wang F F. 2015. The LA-ICP-MS U-Pb chronological characteristics of detrital Zircon which is from Zhiluo Formation in Shiganggou Region in Western Ordos Basin and to determinate its provenance. Journal of Mineralogy and Petrology,35(4): 106-115] [10] 毛光周,刘池洋. 2011. 地球化学在物源及沉积背景分析中的应用. 地球科学与环境学报,233(4): 337-348. [Mao G Z,Liu C Y. 2011. Application of geochemistry in provenance and depositional setting analysis. Journal of Earth Science and Environment,33(4): 337-348] [11] 申浩澈,康维国,梁万通. 1994. 北板块和扬子板块碰撞时代的探讨. 长春地质学院学报,01: 22-27. [Shen H C,Kang W G,Liang W T. 1994. A discussion about the collision time between Northern China Plate and Yangzi Plate.Journal of Changchun University of Earth Science,01: 22-27] [12] 盛继福,陈郑辉,刘丽君,应立娟,黄凡,王登红,王家欢,曾乐. 2015. 中国钨矿成矿规律概要. 地质学报,(6): 1038-1050. [Sheng J F,Chen Z H,Liu L J,Ying L J,Huang F,Wang D H,Wang J H,Zeng L. 2015. Outline of metallogeny of Tungsten deposits in China. Acta Geologica Sinica,(6): 1038-1050] [13] 宋霁,焦养泉,吴立群,汪小妹. 2015. 湖相泥岩型铀矿有利成矿条件分析. 地质科技情报,05: 120-126. [Song J,Jiao Y Q,Wu L Q,Wang X M. 2015. Analysis of advantageous minerogenic conditions of lacustrine mudstone-type Uranium deposit. Geological Science and Technology Information,05: 120-126] [14] 宋健,赵省民,陈登超,邓坚,苗忠英,明承栋,陆程. 2012. 内蒙古西部额济纳旗及邻区二叠纪暗色泥岩微量元素和稀土元素地球化学特征. 地质学报,86(11): 1773-1780. [Song J,Zhao X M,Chen D C,Deng J,Miao Z Y,Ming C D,Lu C. 2012. Rare earth and trace elements geochemical characteristics of the dark Permian mudstones in Ejinaqi and its surrounding areas,Western Inner Mongolia. Acta Geologica Sinica,86(11): 1773-1780] [15] 田洋,赵小明,王令占,涂兵,谢国刚,曾波夫. 2015. 鄂西南利川三叠纪须家河组地球化学特征及其对风化、物源与构造背景的指示. 岩石学报,31(1): 261-272. [Tian Y,Zhao X M,Wang L Z,Tu B,Xie G G,Zeng B F. 2015. Geochemistry of clastic rocks from the Triassic Xujiahe Formation,Lichuan area,southwestern Hubei: Implications for weathering,provenance and tectonic setting. Acta Petrologica Sinica,31(1): 261-272] [16] 王欣欣,郑荣才,闫国强,王昌勇,陈浩如. 2014. 基于稀土元素地球化学特征的泥岩沉积环境及物源分析:以鄂尔多斯盆地陇东地区长9油层组泥岩为例. 天然气地球科学,25(9): 1387-1394. [Wang X X,Zheng R C,Yan G Q,Wang C Y,Chen H R. 2014. The mudstone sedimentary environment and provenance analysis based on the geochemical evidence of rare earth element: Take Chang 9 oil-bearing layer Longdong Area of Ordos Basin as example. Natural Gas Geoscience,25(9): 1387-1394] [17] 汪洋. 2005. 中国大陆部分构造单元出露地壳与全球大陆上地壳化学成分的比较: 对地壳演化的制约和思考. 地质通报,24(10): 906-915. [Wang Y. 2005. Comparison of element abundances between the exposed crust of the continent of China and the global average continental upper crust: Constraints on the crustal evolution and some speculations. Geological Bulletin of China,24(10): 906-915] [18] 王中刚,于学远,赵振华. 1989. 稀土元素地球化学. 北京: 科学出版社. [Wang Z G,Yu X Y,Zhao Z H. 1989. Rare Earth Element Geochemistry. Beijing: Science Press] [19] 魏亮,郭华明,谢振华,李志萍. 2010. 北京平原沉积物稀土元素地球化学特征及物源意义. 地学前缘,17(6): 72-80. [Wei L,Guo H M,Xie Z H,Li Z P. 2010. Rare earth elements geochemistry and its implication for sediment provenance in the Beijing Plain. Earth Science Frontiers,17(6): 72-80] [20] 熊小辉,肖加飞. 2011. 沉积环境的地球化学示踪. 地球与环境,39(3): 405-414. [Xiong X H,Xiao J F. 2011. Geochemical indicators of sedimentary environments: A Summary. Earth and Environment,39(3): 405-414] [21] 徐亚军,杜远生,杨江海. 2013. 北祁连造山带晚奥陶世—泥盆纪构造演化: 碎屑锆石年代学证据. 地球科学(中国地质大学学报),38(5): 934-946. [Xu Y J,Du Y S,Yang J H. 2013. Tectonic evolution of the North Qilian Orogenic Belt from the Late Ordovician to Devonian: Evidence from detrital zircon geochronology. Earth Science (Journal of China University of Geosciences),38(5): 934-946] [22] 许中杰,程日辉,王嘹亮,张莉. 2015. 粤东晚三叠世小水组早侏罗世金鸡组古气候及构造背景的矿物和地球化学记录. 吉林大学学报: 地球科学版,45(3): 712-723. [Xu Z J,Cheng R H,Wang L L,Zhang L. 2015. Mineral and elemental geochemistry records of the paleoclimate and the tectonic background in Late Triassic Xiaoshui Formation Early Jurassic Jinji Formation in East Guangdong. Journal of Jilin University(Earth Science Edition),45(3): 712-723] [23] 鄢明才,迟清华. 1997. 中国东部地壳与岩石的化学组成. 北京: 科学出版社,1997. [Yan M C,Chi Q H. 1997. The Composition of Continental Crust and Rocks of East China. Beijing: Science Press] [24] 杨华,陶家庆,欧阳征健,李刚,景春利. 2011. 鄂尔多斯盆地西缘构造特征及其成因机制. 西北大学学报(自然科学版),41(5): 863-868. [Yang H,Tao J Q,Ouyang Z J,Li G,Jing C L. 2011. Structural characteristics and forming mechanism in the western margin of the Ordos Basin. Journal of Northwest University(Natural Science Edition),41(5): 863-868] [25] 杨江海,杜远生,徐亚军. 2008. 北祁连东段景泰地区下古生界两套砂岩微量元素和稀土元素特征及其构造意义. 古地理学报,10(4): 395-408. [Yang J H,Du Y S,Xu Y J. 2008. Two suits of sandstones in the Lower Paleozoic at Jingtai,eastern North Qilian: Trace and rare earth elements characteristics and tectonic setting. Journal of Palaeogeography (Chinese Edition),10(4): 395-408] [26] 杨守业,韦刚健,夏小平,孙敏,唐珉. 2007. 长江口晚新生代沉积物的物源研究: REE和Nd同位素制约. 第四纪研究,27(3): 339-346. [Yang S Y,Wei G J,Xia X P,Sun M,Tang M. 2007. Provenance study of the Late Cenozoic sediments in the Chang jiang delta: REE and Nd isotopic constraints. Quaternary Sciences,27(3): 339-346] [27] 张进,马宗晋,任文军. 2000. 鄂尔多斯盆地西缘逆冲带南北差异的形成机制. 大地构造与成矿学,24(2): 124-133. [Zhang J,Ma Z J,Ren W J. 2000. The mechanism of the difference between the northern part and the southern part of the fold and thrust belt on the western edge of the Ordos Basin,China. Geotectonica et Meallogenia,24(2): 124-133] [28] 张金亮,张鑫. 2006. 塔里木盆地志留系古海洋沉积环境的元素地球化学特征. 中国海洋大学学报(自然科学版),36(2): 200-208. [Zhang J L,Zhang X. 2006. The element geochemical features of ancient oceanic sedimentary environments in the Silurian Period in the Tarim Basin. Periodical of Ocean University of China(Natural Science Edition),36(2): 200-208] [29] 张文,吴泰然,冯继承,郑荣国,贺元凯. 2013. 阿拉善地块北缘古大洋闭合的时间制约: 来自乌力吉花岗岩体的证据. 中国科学: 地球科学,43: 1299-1311. [Zhang W,Wu T R,Feng J F,Zheng R G,He Y K. 2013. Time constraints for the closing of the Paleo-Asian Ocean in the Northern Alxa Region: Evidence from Wuliji granites. Scientia Sinica Terrae,56: 153-164] [30] 张义楷,周立发,党犇,孙伟. 2006. 鄂尔多斯盆地中新生代构造应力场与油气聚集. 石油实验地质,28(3): 215-219. [Zhang Y K,Zhou L F,Dang B,Sun W. 2006. Relationship between the mesozoic and cenozoic tectonic stress fields and the hydrocarbon accumulation in the ordos basin. Petroleum Geology and Experiment,28(3): 215-219] [31] 赵俊峰. 2007. 鄂尔多斯盆地直罗—安定期原盆恢复. 西北大学博士学位论文. [Zhao J F. 2007. Restoration of the Primary Ordos basin in Zhiluo-Anding Period. Doctoral Dissertation of Northwest University] [32] 郑刘根,刘桂建,高连芬,彭子成. 2006. 中国煤中砷的含量分布、赋存状态、富集及环境意义. 地球学报,27(4): 355-366. [Zheng L G,Liu G J,Gao L F,Peng Z C. 2006. Arsenic in Chinese coals: Its abundance,distribution,modes of occurrence,enrichment processes,and environmental significance. Acta Geoscientica Sinica,27(4): 355-366] [33] Allègre C J,Minster J F. 1978. Quantitative Models of Trace Element Behavior in Magmatic Processes. Earth and Planetary Science Letters,38(1): 1-25. [34] Bhatia M R,Keith A. W. Crook. 1986. Trace element characteristics of graywackes and tectonic setting discrimination of sedimentary basins. Contrib Mineral Petrol,92: 181-193. [35] Dou Y,Yang S,Liu Z,Clift P,Shi X,Yu H,Berne S. 2010. Provenance discrimination of siliciclastic sediments in the middle Okinawa Trough since 30,ka: Constraints from rare earth element compositions. Marine Geology,275(1): 212-220. [36] Floyd P A,Leveridge B E. 1987. Tectonic Environment of the Devonian Gramscatho Basin,South Cornwall: Framework mode and geochemical evidence from turbiditic sandstones. Journal of the Geological Society,144(4): 531-542. [37] Gallet S,Jahn B,Lanoe B V V,Dia A,Rossello E. 1998. Loess geochemistry and its implications for particle origin and composition of the upper continental crust. Earth and Planetary Science Letters,156,157-177. [38] Gao S,Luo T C,Zhang B R. 1998. Chemical composition of the continental crust as revealed by studies in East China. Geochimica et Cosmochimica Acta,62(11): 1959-1975. [39] Gromet L P,Dymek R F,Haskin L A,Koeotev R L. 1984. The “North American Shale Composite”Its compilation,major and trace element characteristics. Geochimica et Cosmochimica Acta,48(12): 2469-2482. [40] Johnson M J. 1993. The System Controlling the Composition of Clastic Sediments. In: Johnson M J,Basu A (eds). Processes Controlling the Composition of Clastic Sediments[S.l.]: Geological Society of America Special Paper,1-19. [41] Mclennan S M. 2001. Relationships between the trace element composition of sedimentary rocks and upper continental crust. Geochemistry Geophysics Geosystems,2:1-24. [42] Mclennan S M,Hemming S,McDaniel M J,Hanson G N. 1993. Geochemical approaches to sedimentation,provenance and tectonics. In: Jonhanson M J(ed). Processes Controlling the Composition of Clastic Sediments. Boulder,Colorado: Geological Society of America Special Paper,21-40. [43] Nesbitt H W,Young G M. 1982. Early Proterozoic climates and plate motions inferred from major element chemistry of lutites. Nature,299(5885): 715-717. [44] Nesbitt H W,Young G M. 1989. Formation and diagenesis of weathering profiles. Journal of Geology,97(2): 129-147. [45] Owen L A,Finkelb R C,Barnardc L P,Ma H,Asahi K,Caffee M W,Derbyshire E. 2005. Climatic and topographic controls on the style and timing of Late Quaternary glaciation throughout Tibet and the Himalaya defined by 10Be cosmogenic radionuclide surface exposure dating. Quaternary Science Reviews,24(12-13):1391-1411. [46] Pramod S. 2009. Major,trace and REE geochemistry of the Ganga River sediments influence of provenance and sedimentary processes. Chemical Geology,266:242-255. [47] Roser B P,Korsem R J. 1986. Detemrination of tectonic setting of sandstone: Mudstone suites using SiO2 content and K2O/Na2O ratio. Journal of Geology,94(5):635. [48] Song Y,Cho M. 2009. REE geochemistry of fine-grained sediments from major rivers around the Yellow Sea. Chemical Geology,266:328-342. [49] Taylor S R,Mclennan S M. 1985. The Continental Crust: Its Composition and Evolution. Blackwell Scientific Pub. [50] Taylor S R,Mclennan S M. 1995. The Geochemical Evolution of the Continental Crust. Reviews of Geophysics,33(2):241-265.