Geochemistry characteristics and sedimentary environment of oil shale from the Eocene Bahuli Formation in Liushuhe Basin,Heilongjiang Province
Zheng Yulong1,2, Ma Zhiqiang2, Wang Baichang2, Yuan Guoli1, Qin Jianxun1
1 School of Earth Sciences and Resources, China University of Geosciences(Beijing),Beijing 100083; 2 Daqing Oilfield Mudanjiang New Energy Company Ltd.,Mudanjiang 157032,Heilongjiang
Abstract:Several layers of oil shale were developed in the Eocene Bahuli Formation of Liushuhe Basin,Heilongjiang Province. Based on the characteristics of major,trace and rare earth elements,sedimentary environment of oil shale was analyzed. In the oil shale of Bahuli Formation of Liushuhe Basin,major elements are characterized by rich in Al2O3,Fe and CaO,and poor in SiO2,MgO,Na2O and K2O;trace elements are generally depleted in different degree,and the amount of rare earth elements(REE)averages 140.7×10-6,which show mild enrichment of light rare earth elements. Relatively consistent change trend of rare earth elements indicates that the provenance and sedimentary environment were relatively stable. The ratio of Mn/Ti shows that the transported distance of material composed oil shale experienced changes from far to near,then to far,which reflects that the depth of water changed from deep to shallow,then to deep. The ratios of Sr/Cu and Rb/Sr indicate that the climate was relatively hot and dry. The ratio of Sr/Ba reflects the salt water lake at that time. The ratios of V/(V+Ni),δEu and the content of organic carbon show that the oil shale was developed in the anaerobic reducing sedimentary environment. As a whole,the oil shale in Liushuhe Basin was developed in the lake with the condition of hot and dry climate,salt water and anaerobic reduction.
Zheng Yulong,Ma Zhiqiang,Wang Baichang et al. Geochemistry characteristics and sedimentary environment of oil shale from the Eocene Bahuli Formation in Liushuhe Basin,Heilongjiang Province[J]. JOPC, 2015, 17(5): 689-698.
邓宏文,钱凯. 1993. 沉积地球化学与环境分析[M]. 甘肃兰州:甘肃科学技术出版社,4-97. 顾雪祥,刘建明,Oskar S,等. 2003. 江南造山带雪峰隆起区元古宙浊积岩构造背景的地球化学制约[J]. 地球化学,32(5):406-426. 金章东,沈吉,王苏民,等. 2002. 岱海的“中世纪暖期”[J]. 湖泊科学,24(3):209-216. 刘春莲,秦红,车平,等. 2005. 广东三水盆地始新统布心组生油岩元素地球化学特征及沉积环境[J]. 古地理学报,7(1):125-136. 刘沣,刘昭君,柳蓉,等. 2007. 抚顺盆地始新统计军屯组油页岩地球化学特征及其沉积环境[J]. 世界地质,26(4):441-446. 刘招君,孟庆涛,柳蓉,等. 2009a. 抚顺盆地地始新统计军屯组油页岩地球化学特征及其地质意义[J]. 岩石学报,25(10):2340-2350. 刘招君,杨虎林,董清水,等. 2009b. 中国油页岩[M]. 北京:石油工业出版社,1-334. 刘振文,王佰长,郑玉龙,等. 2010. 黑龙江省柳树河盆地五林勘查区油页岩特征[J]. 大庆石油地质与开发,29(6):34-38. 柳蓉,刘招君,郭巍,等. 2010. 巴格毛德油页岩中稀土元素特征研究及其地质意义[J]. 地球化学,39(4):364-370. 孟庆涛,刘招君,胡菲,等. 2013. 桦甸盆地始新统油页岩稀土元素地球化学特征及其地质意义[J]. 吉林大学学报(地球科学版),43(3):390-399. 彭雪峰,汪立今,姜丽萍. 2012. 准格尔盆地东南缘芦草沟组油页岩元素地球化学特征及沉积环境指示意义[J]. 矿物岩石地球化学通报,31(2):121-127. 沈吉,张恩楼,夏威岚. 2001. 青海湖近千年来气候环境变化的湖泊沉积记录[J]. 第四纪研究,21(6):508-513. 孙林华. 2012. 皖北沟后组页岩地球化学特征及地质意义[J]. 地质调查研究,35(4):268-275. 王东营,许浩,李婧婧,等. 2008. 博格达山北麓大黄山地区芦草沟组油页岩地球化学特征与沉积环境分析[J]. 内蒙古石油化工,(2):62-65. 吴少波. 2001. 博格达山前凹陷上二叠统乌拉泊组沉积相及沉积模式[J]. 沉积学报,19(3):333-339. 张文正,杨华,杨弈华,等. 2008. 鄂尔多斯盆地长7优质烃源岩的岩石学、元素地球化学特征及发育环境[J]. 地球化学,37(1):59-64. 中国科学院地球化学研究所. 2000. 高等地球化学[M]. 北京:科学出版社,378. Bhatia M R. 1985. Plate tectonics and geochemical composition of sandstones[J]. Journal of Geology,91(6):611-627. Cox R,Lowe D R,Cullers R L. 1995. The influence of sediment recycling and basement composition on evolution of mudrock chemistry in the Southwestern United States[J]. Geochimica et Cosmochimica Acta,59(14):2919-2940. Farrimond P,Eglinton G,Brassell S C. 1990. The Cenomanian-Turonian anoxic event in Europe:An organic geochemical study[J]. Mar. Petrol. Geol.,7:75-89. Fedo C M,Nesbitt H W,Young G M. 1995. Unraveling the effects of potassium metasomatism in sedimentary rocks and paleosols,with implications for paleoweathring conditions and provenance[J]. Geology,23(10):921-924. Hatch J R,Leventhal J S. 1992. Relationship between inferred redox potential of the depositional environment and geochemistry of the Dennis Limestone,Wabaunsee County,Kansas,USA[J]. Chemical Geology,99(1):65-82. Jones B,Manning D A C. 1994. Comparison of geological indices used for the interpretation of palaeoredox conditions in ancient mud-stones[J]. Chemical Geology,111:111-129. Margus V,Alvar S,Sigrid H, et al. 2013. Geochemical heterogeneity of estonian graptolite argillite[J]. Oil Shale,30(3):377-401. Taylor S R,Mclennan S M. 1985. The Continental Crust:Its Composition and Evolution[M]. Oxford:Blackwell Scientific Publications,1-312.张西娟