Organic-rich black shales,which represent shale oil and gas resources,have become a research hotspot in the field of oil and gas exploration and development in China and around the world in recent years. These lithologies consist mainly of complexly sourced fine-grained sedimentary rocks in continental lacustrine basins in China,among which a special type of laminated microcrystalline dolostone is developed. The petrological,mineralogical micro-features,and geochemical characteristics of this type of dolostone are distinct from the commonly dolostones formed by dolomitization and are also different from microbial mediated dolostones. Hence,the dolostones have been defined as a new type of volcanic-hydrothermal sedimentary dolostone. Based on extensive review of domestic and foreign literature,this paper summarizes the global distribution and environmental characteristics of modern lacustrine dolomites and presents the research progress on the models of origins of dolostone. The focus is on the comparative study of volcanic-hydrothermal sedimentary dolostones found in the Lucaogou Formation in Santanghu and Junggar Basins, the Xiagou Formation in Jiuxi Basin,and the Tengger Formation in Erlian Basin,all of which are formed in an extensional tectonic setting. Four characteristics are summarized as follows: (1)These dolostones are well-preserved with μm-scale laminated structure and microcrystallized,indicating latterly weak diagenesis. (2)They contain a variety of volcanic-hydrothermal minerals,and are interbedded with semi-deep to deep lacustrine black shale. Evaporite characteristics are lacking. (3)Strontium isotopes indicate that the diagenetic fluid has a deep source(crust-mantle mixed)characteristic. (4)They are rich in organic matters and show a strong coupling relationship with hydrocarbon distribution. Finally,it is recommended to enhance research on this type of dolostone,utilize its unique geological information for tracing tectonic backgrounds,and explore its relationship with hydrocarbon generation as future research directions.
The exploration and development of marine-continental transitional shale gas is in the primary stage. The Shanxi-Taiyuan Formations shale has good hydrocarbon generation potential and is also an important horizon for the development of marine-continental transitional shale gas in China. In order to explore the relationship between sedimentary environment and organic matter enrichment of the Shanxi-Taiyuan Formations shale in the western Linqing Depression,Bohai Bay Basin,Well XJ1 was investigated in detail by means of petrology,organic geochemistry,element geochemistry and numerical analysis. The results show that the Shanxi-Taiyuan Formations shale is characterized by a low content of brittle minerals,a high content of clay minerals and a high resistance to hydraulic fracturing. It is also found that the Shanxi-Taiyuan Formations shale comprises a high-quality source rock with an average TOC content of 4.03%,which has the potential for shale gas exploration and development. During the deposition of the Taiyuan Formation mudstone/shale,the study area featured an anoxic,moderately stagnant oceanic environment under a warm and humid climate,with frequent variaions in terrigenous debris influx,low deposition rate and low to medium paleoproductivity level. During the deposition of the Shanxi Formation mudstone/shale,the study area featured anoxic,moderately to strongly stagnant and brackish to brine seawater under complex and ever-changing paleoclimatic conditions,with a stable and high terrigenous debris influx,medium deposition rate and medium to high paleoproductivity level. Given the linear correlation,grey correlation and robust regression analysis between paleoenvironmental conditions and TOC content,it is concluded that the enrichment of organic matter in the Taiyuan shale is mainly controlled by paleoclimate,paleoredox and ancient water salinity conditions,while the enrichment of organic matter in the Shanxi shale is mainly controlled by paleoclimate and terrigenous debris input conditions.